Citation: LIU Zhitong, ZHANG Bing, WANG Wenwen, LIU Guorui, GAO Lirong, ZHENG Minghui. Determination of polychlorinated naphthalenes in environmental samples by isotope dilution gas chromatography-triple quadrupole mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(9): 878-884. doi: 10.3724/SP.J.1123.2013.02012 shu

Determination of polychlorinated naphthalenes in environmental samples by isotope dilution gas chromatography-triple quadrupole mass spectrometry

1.
1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;

Corresponding author: ZHENG Minghui,
Received Date: 6 February 2013
Available Online: 25 March 2013
Fund Project: 国家自然科学基金项目(21107123,21007084). (21107123,21007084)

An isotope dilution gas chromatography combined with triple quadrupole mass spectrometry (GC-MS/MS) method was established for the analysis of twenty polychlorinated naphthalenes (PCNs) congeners in environmental samples. The linear correlation coefficients (R²) of calibration curves were greater than 0.99 in the concentration range of 0.5-200 μg/L for all the twenty PCN congeners. The average relative response factors (RRF) were calculated based on a seven-point calibration for the twenty PCN congeners. The relative standard deviations (RSDs) of all the congeners were below 15% (n=7). The limits of detection (LOD) of the established method ranged from 0.04 to 0.48 μg/L for the twenty PCN congeners. The recoveries of matrix spiked samples ranged from 45.2% to 87.9%, and the RSDs ranged from 0.4% to 21.2%. The sediment samples and stack gas samples collected from secondary aluminum smelting were analyzed by the established method. The obtained results were also compared with the data analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) method. The comparison indicated that the data of the established method was in good agreement with those of HRGC/HRMS method with the RSDs of 0.5%-41.4%. Consequently, the established GC-MS/MS method can be applied to the determination of PCNs in environmental samples.
1. [1]
  [1] Nie Z, Zheng M, Liu W, et al. Chemosphere, 2011, 85(11): 1707
2. [2]
  [2] Hu J, Zheng M, Liu W, et al. Environ Sci Poll Res, 2013, 20(5): 2905
3. [3]
  [3] Ba T, Zheng M H, Zhang B, et al. Environ Sci Technol, 2010, 44(7): 2441
4. [4]
  [4] Kannan K, Imagawa T, Blankenship A L, et al. Environ Sci Technol, 1998, 32(17): 2507
5. [5]
  [5] Lewis R G, Brown A R, Jackson M D. Anal Chem, 1977, 49(12): 1668
6. [6]
  [6] Wang D, Atkinson S, Hoover-Miller A, et al. J Hazard Mater, 2012, 223/224: 72
7. [7]
  [7] Castells P, Parera J, Santos F J, et al. Chemosphere, 2008, 70(9): 1552
8. [8]
  [8] Li Q L, Xu Y, Li J, et al. Atmos Environ, 2012, 56: 228
9. [9]
  [9] Wang Y, Cheng Z, Li J, et al. Environ Poll, 2012, 170: 1
10. [10]
  [10] Hogarh J N, Seike N, Kobara Y, et al. Chemosphere, 2012, 86(7): 718
11. [11]
  [11] Nadal M, Schuhmacher M, Domingo J L. Environ Poll, 2011, 159(7): 1769
12. [12]
  [12] Liu G R, Cai M W, Zheng M H, et al. Bull Environ Contam Tox, 2011, 86(5): 535
13. [13]
  [13] Zhao X, Zhang H, Fan J, et al. Marine Poll Bull, 2011, 62(5): 918
14. [14]
  [14] Helm P A, Milne J, Hiriart-Baer V, et al. J Great Lakes Res, 2011, 37(Suppl 3): 132
15. [15]
  [15] Rotander A, van Bavel B, Riget F, et al. Environ Poll, 2012, 164: 118
16. [16]
  [16] Fernandes A, Tlustos C, Rose M, et al. Chemosphere, 2011, 85(3): 322
17. [17]
  [17] Wu J J, Zhang B, Dong S J, et al. Chinese Journal of Analytical Chemistry (吴嘉嘉, 张兵, 董姝君, 等. 分析化学), 2011, 39(9): 1297
18. [18]
  [18] Luo C H, Guo Z S, Sun J. Chinese Journal of Chromatography (罗财红, 郭志顺, 孙静. 色谱), 2010, 28(5): 487
19. [19]
  [19] Guo L, Zhang B, Xiao K, et al. Chinese Science Bulletin, 2008, 53(4): 508
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
3. [3]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
4. [4]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
5. [5]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
6. [6]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
7. [7]
  Zongyuan Chen , ChunSheng Shi , Yiwen Li , Ganlin Zu , Qiang Jin , Haishan Wang , Fujun Wang , Dekun Yan , Zhijun Guo , Wangsuo Wu . Measurement of Uranium Isotopes in Environmental Water Samples by Alpha-Spectroscopy: Design of an Undergraduate Radiochemistry Experiment. University Chemistry, 2025, 40(4): 353-358. doi: 10.12461/PKU.DXHX202406103
8. [8]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
9. [9]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
10. [10]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
11. [11]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
12. [12]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
13. [13]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
14. [14]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
15. [15]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
16. [16]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
17. [17]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
18. [18]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
19. [19]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
20. [20]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(553)
HTML views(128)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142