Citation: XIE Yuan-Yuan, HUA Lei, HOU Ke-Yong, CHEN Ping, CUI Hua-Peng, ZHAO Wu-Duo, CHEN Wen-Dong, LI Jing-Hua, LI Hai-Yang. On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(12): 1883-1889. doi: 10.3724/SP.J.1096.2012.20542 shu

On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry

XIE Yuan-Yuan ^1,2 ,
HUA Lei ¹ ,
HOU Ke-Yong ¹ ,
CHEN Ping ^1,2 ,
CUI Hua-Peng ^1,2 ,
ZHAO Wu-Duo ^1,2 ,
CHEN Wen-Dong ^1,2 ,
LI Jing-Hua ¹ ,
LI Hai-Yang ^1,,

1.
¹ Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;

Corresponding author: LI Hai-Yang,
Received Date: 25 May 2012
Available Online: 13 July 2012
Fund Project: 重大科学仪器设备(No.2011YQ05006904) (No.2011YQ05006904)"863"计划(No.2011AA060602)以及国家自然科学基金(No.20907052)资助项目 (No.2011AA060602)以及国家自然科学基金(No.20907052)

A new method was developed for the on-line analysis of flavor compounds in toothpastes without any sample preparation by direct injection time-of-flight mass spectrometry with single photon ionization (SPI-TOFMS). The samples were directly taken into the ionization source by the quartz capillary tube and the pressure condition of the ionization source was optimized. Under the discrimination of characteristic mass spectra of flavor compounds, rapid and accurate identification of flavors in toothpastes was achieved. The analysis time for a single sample was only 0.5 min. This method was applied to on-line and in-situ monitoring of flavor compounds during tooth brushing process. The influence of water content on release of flavor compounds from toothpastes was studied. The results indicate that direct injection SPI-TOFMS can monitor the composition and concentration of flavor compounds in real time. The method could be suitable to analyze the flavors from various samples such as food and cosmetics.
- On-line analysis,
- Single photon ionization,
- On-line time-of-flight mass spectrometry,
- Toothpaste,
- Flavor compounds
1. [1]
  1 Robinson R S, Tavss E A, Santalucia J, Carroll D LJ. Chromatogr. A, 1988, 455: 143-149
2. [2]
  2 Tavss E A, Wiet S G, Robinson R S, Santalucia J, Carroll D L. J. Chromatogr. A, 1988, 438: 273-280
3. [3]
  3 Jordan M J, Margaria C A, Shaw P E, Goodner K L. J. Agric. Food Chem., 2002, 50(19): 5386-5390
4. [4]
  4 Galle S A, Koot A, Soukoulis C, Cappellin L, Biasioli F, Alewijn M, van Ruth S M. J. Agric. Food Chem., 2011, 59: 2554-2563
5. [5]
  5 Savary G, Lafarge C, Doublier J L, Cayot N. Food Res. Int., 2007, 40 (6): 709-716
6. [6]
  6 CHEN Huan-Wen, ZHENG Jian, WANG Wei-Ping, CHEN Chang-Lin, WANG Zhi-Chang. Chinese J. Anal. Chem., 2009, 37(2):237-241
7. [7]
  陈焕文, 郑健, 王伟萍, 陈昌林, 王志畅. 分析化学, 2009, 37(2): 237-241
8. [8]
  7 CHEN Huan-Wen, ZHANG Xie, LUO Ming-Biao. Chinese J. Anal Chem., 2006, 34(4): 464-468
9. [9]
  陈焕文, 张燮, 罗明标. 分析化学, 2006, 34(4): 464-468
10. [10]
  8 XIE Li, YU Jiang, REN Peng-Gang, DIAO Sha-Sha, LI Shuang. Chinese J. Anal. Chem., 2011, 39(9): 1368-1372
11. [11]
  谢利, 于江, 任鹏刚, 刁沙沙, 李爽. 分析化学, 2011, 39(9): 1368-1372
12. [12]
  9 MA Qiang, XI Hai-Wei, WANG Chao, BAI Hua, XI Guang-Cheng, SU Ning, XU Li-Yan, WANG Jun-Bing. Chinese J. Anal. Chem., 2011, 39(8): 1201-1207
13. [13]
  马强, 席海为, 王超, 白桦, 席广成, 苏宁, 徐丽艳, 王军兵. 分析化学, 2011, 39(8): 1201-1207
14. [14]
  10 Muhlberger F, Wieser J, Ulrich A, Zimmermann R. Anal. Chem., 2002, 74(15): 3790-3801
15. [15]
  11 Geissler R, Saraji-Bozorgzad M R, Groger T, Fendt A, Streibel T, Sklorz M, Krooss B M, Fuhrer K, Gonin M, Kaisersberger E, Denner T, Zimmermann R. Anal. Chem., 2009, 81(15): 6038-6048
16. [16]
  12 CUI Hua-Peng, HOU Ke-Yong, WU Qing-Hao, HUA Lei, CHEN Ping, JU Bang-Yu, LI Lin, WANG Zhen-Xin, LI Jing-Hua, LI Hai-Yang. Chinese J. Anal. Chem., 2010, 38(5): 760-764
17. [17]
  崔华鹏, 侯可勇, 吴庆浩, 花磊, 陈平, 鞠帮玉, 李林, 王帧鑫, 李京华, 李海洋. 分析化学, 2010, 38(5): 760-764
18. [18]
  13 HUA Lei, WU Qing-Hao, HOU Ke-Yong, CUI Hua-Peng, CHEN Ping, ZHAO Wu-Duo, XIE Yuan-Yuan, LI Hai-Yang. Environmenal Science, 2011, 32(12): 167-173
19. [19]
  花磊, 吴庆浩, 侯可勇, 崔华鹏, 陈平, 赵无垛, 谢园园, 李海洋. 环境科学, 2011, 32(12): 167-173
20. [20]
  14 Tsuruga S, Suzuki T, Takatsudo Y, Seki K, Yamuchi S, Kuribayashi S, Morii S. Environ. Sci. Technol., 2007, 41(10): 3684-3688
21. [21]
  15 Muhlberger F, Streibel T, Wieser J, Ulirch A, Zimmerman R. Anal. Chem., 2005, 77(22): 7408-7414
22. [22]
  16 Streibel T, Geissler R, Saraji-Bozorgzad M, Sklorz M, Kaisersberger E, Denner T, Zimmermann R. J. Therm Anal. Calorim, 2009, 96(3): 795-804
23. [23]
  17 Schramm E, Kurten A, Holzer J, Mitschke S, Muhlberger F, Sklorz M, Zimmermann R. Anal.Chem., 2009, 81(11): 4456-4467
24. [24]
  18 Buffo R A, Zehentbauer G, Reineccius G A. J. Agric. Food Chem., 2005, 53: 702-707
25. [25]
  19 Hua L, Wu Q H, Hou K Y, Cui H P, Chen P, Wang W G, Li J H, Li H Y. Anal. Chem., 2011, 83(13): 5309-5316
26. [26]
  20 Finkelshtein E I. J. Phys. Org. Chem., 2001, 14(8): 543-550
27. [27]
  21 MENG Ling-Zhi, GONG Shu-Ling, HE Yong-Bing. Organic Spectral Analysis. Wuhan:Wuhan University Press, 2003: 23-33
28. [28]
  孟令芝, 龚淑玲, 何永炳. 有机波谱分析. 武汉: 武汉大学出版社, 2003: 23-33
29. [29]
  22 Bylaite E, Adler-Nissen J, Meyer A S. J. Agric. Food Chem., 2005, 53 (9): 3577-3583
30. [30]
  23 Gierczynski I, Labouré H, Sémon E, Guichard E. J. Agric. Food Chem., 2007, 55(8): 3066-3073
31. [31]
  24 Dold S, Lindinger C, Kolodziejczyk E, Pollien P, Ali S, Germain J C, Perin S G, Pineau N, Folmer B, Engel K H, Barron D, Hartmann C. J. Agric. Food Chem., 2011, 59(20): 11196-11203
1. [1]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
2. [2]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
3. [3]
  Yuhang Jiang , Weijie Liu , Jiaqi Cai , Jiayue Chen , Yanping Ren , Pingping Wu , Liulin Yang . A Journey into the Science and Art of Sugar: “Dispersion of Light and Optical Rotation of Matter” Science Popularization Experiment. University Chemistry, 2024, 39(9): 288-294. doi: 10.12461/PKU.DXHX202401054
4. [4]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
5. [5]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
6. [6]
  Pingwei Wu . Application of Diamond Software in Simplex Teaching. University Chemistry, 2024, 39(3): 118-121. doi: 10.3866/PKU.DXHX202311043
7. [7]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
8. [8]
  Zhenli Sun , Ning Wang , Kexin Lin , Qin Dai , Yufei Zhou , Dandan Cao , Yanfeng Dang . Visual Analysis of Hotspots and Development Trends in Analytical Chemistry Education Reform. University Chemistry, 2024, 39(11): 57-64. doi: 10.12461/PKU.DXHX202403095
9. [9]
  Zhaoyang Li , Haiyan Zhao , Yali Zhang , Yuan Zhang , Shiqiang Cui . Integration of Nobel Prize Achievements in Analytical Technology with College Instrumental Analysis Course. University Chemistry, 2025, 40(3): 269-276. doi: 10.12461/PKU.DXHX202405131
10. [10]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
11. [11]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
12. [12]
  Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
13. [13]
  Yan Zhang , Ping Wang , Tiebo Xiao , Futing Zi , Yunlong Chen . Measures for Ideological and Political Construction in Analytical Chemistry Curriculum. University Chemistry, 2024, 39(4): 255-260. doi: 10.3866/PKU.DXHX202401017
14. [14]
  Xiaofei Zhou , Yu-Qing Cao , Feng Zhu , Li Qi , Linhai Liu , Ni Yan , Zhiqiang Zhu . Missions and Challenges of Instrumental Analysis Course in the New Era. University Chemistry, 2024, 39(6): 174-180. doi: 10.3866/PKU.DXHX202310058
15. [15]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(12): 0-0.
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
18. [18]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
19. [19]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
20. [20]
  Lijun Dong , Pengcheng Du , Guangnong Lu , Wei Wang . Exploration and Practice of Independent Design Experiments in Inorganic and Analytical Chemistry: A Case Study of “Preparation and Composition Analysis of Tetraammine Copper(II) Sulfate”. University Chemistry, 2024, 39(4): 361-366. doi: 10.3866/PKU.DXHX202310041

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(356)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142