Citation: JIA Chen-Zhong, WANG Yan-Xing, ZHANG Cai-Xiang. Variation Characteristics of 3D-Excition Emission Matrix Fluorescence Spectra of Dissolved Organic Matter from Landfill Leachate during Photocatalytic Degradation[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1740-1746. doi: 10.3724/SP.J.1096.2012.20409 shu

Variation Characteristics of 3D-Excition Emission Matrix Fluorescence Spectra of Dissolved Organic Matter from Landfill Leachate during Photocatalytic Degradation

1.
¹ College of Chemical and Environmental Engineering, Yangtze University, Jingzhou 434023, China;

Corresponding author: JIA Chen-Zhong,
Received Date: 18 April 2012
Available Online: 23 June 2012
Fund Project: 本文系国家自然科学基金项目(No. 40972156) (No. 40972156)中国地质大学(武汉)生物地质与环境地质教育部重点实验室开放项目(No. BGEGF200820) (武汉)生物地质与环境地质教育部重点实验室开放项目(No. BGEGF200820)

Three-dimensional excitation emission matrix fluorescence spectroscopy (3D-EEMs) was applied to analyze the variation characteristics of dissolved organic matter (DOM) six fractions in landfill leachate during photocatalytic degradation. The results showed that fluorescence spectroscopy of hydrophobic acids (HOA), hydrophobic bases (HOB), hydrophobic neutral traction (HIB), hydrophobic neutral fraction (HON) and hydrophilic neutral fraction (HIN) changed considerably, and that of HIA was relatively steady during photocatalytic process. In general, fluorescence peaks of humic acids-like had the most significant change during photocatalytic treatment process, and disappeared entirely after 60 h treatment, which implied that humic acids-like can be degraded preferentially. In 72 h effluent, VIS fulvic-like, tryptophan-like and tyrosine-like were residual in the fluorescence regions, and the last two were predominant fractions. These results indicated that macromolecular fulvic-like and humic acids-like can be degraded into micro-molecular protein-like matters.
- Landfill leachate,
- Dissolved organic matter,
- Photocatalysis,
- Fraction,
- Three dimentional excitation emission matrix fluorescence spectroscopy
1. [1]
  1 Huo S L, Xi B D, Yu H C, He L S, Fan S L, Liu H G. J. Environ. Sci., 2008, 20(4): 492-498
2. [2]
  2 Liu T, Chen Z L, Yu W Z, You S J. Water Res, 2011, 45(5), 2111-2121
3. [3]
  3 WU Jin, CUI Shuo, SU Wei, CAO Zhi-Ping. Spectroscopy and Spectral Analysis, 2011, 31(6): 1562-1566
4. [4]
  吴静, 崔硕, 苏伟, 曹知平. 光谱学与光谱分析, 2011, 31(6): 1562-1566
5. [5]
  4 Lu F, Chang C H, Lee D J, He P J, Shao L M, Su A. Chemosphere, 2009, 74(4): 575-582
6. [6]
  5 LV Gui-Cai, ZHAO Wei-Hong, WANG Jiang-Tao. Chinese J. Anal. Chem., 2010, 38(8): 1144-1150
7. [7]
  吕桂才, 赵卫红, 王江涛. 分析化学, 2010, 38(8): 1144-1150
8. [8]
  6 ZHANG Jun-Zheng, YANG Qian, XI Bei-Dou, WEI Zi-Min, HE Xiao-Song, LI Ming-Xiao, YANG Tian-Xue. Spectroscopy and Spectral Analysis, 2008, 28(11): 2583-2587
9. [9]
  张军政, 杨谦, 席北斗, 魏自民, 何小松, 李鸣晓, 杨天学. 光谱学与光谱分析, 2008, 28(11): 2583-2587
10. [10]
  7 HE Xiao-Song, XI Bei-Dou, WEI Zi-Min, LI Ming-Xiao, GENG Chun-Mao, YU Hong, LIU Hong-Liang. Chinese J. Anal. Chem., 2010, 38(10): 1417-1422
11. [11]
  何小松, 席北斗, 魏自民, 李鸣晓, 耿春茂, 余红, 刘鸿亮. 分析化学, 2010, 38(10): 1417-1422
12. [12]
  8 Lee J M, Kim M S, Kim B W. Water Res, 2004, 38(16): 3605-3613
13. [13]
  9 de Morais J L, Zamora P P. J. Hazard Mater, 2005, 123(1-3): 181-186
14. [14]
  10 Lou Z Y, Zhao Y C, Yuan T, Song Y, Chen H L, Zhu N W, Huan R H. Sci. Total Environ., 2009, 407(10): 3385-3391
15. [15]
  11 WEI Qiong-Shan, WANG Dong-Sheng, YU Jian-Feng, LIU Hai-long, HAN Hong-Da, HE Wen-Jie. Techniques and Equipment for Environmental Pollution Control, 2006, 7(10): 17-21, 82
16. [16]
  魏群山, 王东升, 余剑锋, 刘海龙, 韩宏大, 何文杰. 环境污染治理技术与设备, 2006, 7(10): 17-21, 82
17. [17]
  12 Jia C Z, Wang Y X, Zhang C X, Qin Q Y. Water, Air, & Soil Pollution, 2010, 217(1): 375-385
18. [18]
  13 Liu Z P, Guo J S, Fang F. Advanced Materials Research, 2011, 233(5): 667-672
19. [19]
  14 Tauchert E, Schneider S, de Morais J L, Peralta-Zamora P. Chemosphere, 2006, 64(9): 1458-1463
20. [20]
  15 Hudson N, Baker A, Reynolds D. River Research and Applications, 2007, 23(6): 631-649
21. [21]
  16 Uyguner CS, Bekbolet M. Catal Today, 2005, 101(3-4): 267-274
22. [22]
  17 Her N, Amy G, Chung J, Yoon J, Yoon Y. Chemosphere, 2008, 70(3): 495-502
23. [23]
  18 Swietlik J, Sikorska E. Water Res., 2004, 38(17): 3791-3799
24. [24]
  19 Coble P G. Mar Chem., 1996, 51(4): 325-346
1. [1]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
2. [2]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
3. [3]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
4. [4]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
5. [5]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
6. [6]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
9. [9]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
10. [10]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
11. [11]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
12. [12]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
13. [13]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
16. [16]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
17. [17]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
18. [18]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
19. [19]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
20. [20]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(442)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142