Citation: LENG Geng, LÜ Gui-Bin, CHEN Yong, YIN Hui, DAN De-Zhong. Determination of Polycyclic Aromatic Hydrocarbons in Sediment by High Performance Liquid Chromatography Following Vortex-Assisted Extraction Combined with Dispersive Liquid-Liquid Microextraction[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1752-1757. doi: 10.3724/SP.J.1096.2012.20398 shu

Determination of Polycyclic Aromatic Hydrocarbons in Sediment by High Performance Liquid Chromatography Following Vortex-Assisted Extraction Combined with Dispersive Liquid-Liquid Microextraction

LENG Geng ¹ ,
LÜ Gui-Bin ² ,
CHEN Yong ² ,
YIN Hui ² ,
DAN De-Zhong ^1,,

1.
¹ College of Architecture and Environment, Sichuan University, Chengdu 610065, China;

Corresponding author: DAN De-Zhong,
Received Date: 16 April 2012
Available Online: 26 June 2012

A simple and rapid method, vortex-assisted extraction (VAE) followed by dispersive liquid-liquid microextraction (DLLME) has been developed for the extraction of polycyclic aromatic hydrocarbons (PAHs) in sediment samples prior to analysis by high performance liquid chromatography (HPLC)-fluorescence detection (FLD). Effects of significant parameters, such as type and volume of extraction and disperser solvent, extraction time, salt content and pH value, were optimized. Under the optimum conditions, the limits of detection (LODs) ranged from 2.3 to 6.8 ng/g, the linearity ranged from 10 to 2100 ng/g, coefficients of determinations (R²) ranged from 0.9986 to 0.9994. The average recoveries of PAHs in sediment samples spiking with 3 different concentration levels were 85.2%±4.7%, 85.0%±5.0% and 85.0%±5.1%, respectively, and the relative standard deviations were 5.7%, 6.1% and 5.7%, respectively. The proposed method was successfully applied in analysis of real nature sediment samples. PAHs were detected in all real nature sediment samples collecting from 3 different depths, the average amount in sediment samples were 73.3, 49.8 and 28.3 ng/g, respectively and the average recoveries was 84.8%±4.8%, 83.1%±4.7% and 84.6%±4.6%, respectively.
1. [1]
  1 Mohammad R, Yaghoub A, Mohammad R M H, Elham A, Fardin A, Sana B. J. Chromatogr. A, 2006, 1116(1-2): 1-9
2. [2]
  2 Wang C, Wu Q H, Wu C X, Wang Z. J. Hazard. Mater., 2011, 185(1): 71-76
3. [3]
  3 Cunha S C, Fernandes J O. Talanta, 2010, 83 (1): 117-125
4. [4]
  4 Yan H Y, Wang H, Qin X Y, Liu B M, Du J J. J. Pharm. Biomed. Anal., 2011, 54 (1): 53-57
5. [5]
  5 Hassan S, Vahid K, Soheila S. Talanta, 2011, 83 (3): 885-890
6. [6]
  6 Aristidis N A, Kallirroy I G I. Anal. Chim. Acta, 2010, 668 (1): 35-40
7. [7]
  7 Seyed R Y, Farzaneh S. Anal. Chem. Acta, 2010, 669 (1-2): 25-31
8. [8]
  8 ZHANG Yan-Jie, BAI Xiao-Hong, LI Li-Hua, WANG Quan-De. Chinese J. Anal. Chem., 2009, 37(12): 1805-1809
9. [9]
  张彦杰, 白小红, 李利华, 王泉德. 分析化学, 2009, 37(12): 1805-1809
10. [10]
  9 Mohammad R, Yadollah Y, Morteza M, Abolfazl S, Mohammad F, Mohammad H N. J. Supercrit. Fluids, 2010, 55 (1): 161-168
11. [11]
  10 Verónica P, Juan H A, Ana M A, Venerando G. Talanta, 2001, 54 (1): 15-23
12. [12]
  11 Patricia N, Nestor E, Gorka A. Anal. Chim. Acta, 2009, 648 (2): 178-182
13. [13]
  12 Verónica P, Jared L A, Juan H A, Venerando G, Ana M A. J. Chromatogr. A, 2008, 1182 (2): 145-152 13 Verónica P, Juan H A, Ana M A, Venerando G. J. Chromatogr. A, 2000, 869 (1-2): 515-522
14. [14]
  14 González V F, Graña E C, Lorenzo S M, Mahía P L, Rodríguez D P. J. Chromatogr. A, 2008, 1196-1197: 65-72
15. [15]
  15 Mark R B, Steven D Z, Teresa L B, Mary C O, Jana L I. Anal. Chim. Acta, 2005, 549 (1-2): 104-116
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
3. [3]
  Siming Bian , Sijie Luo , Junjie Ou . Application of van Deemter Equation in Instrumental Analysis Teaching: A New Type of Core-Shell Stationary Phase. University Chemistry, 2025, 40(3): 381-386. doi: 10.12461/PKU.DXHX202406087
4. [4]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
7. [7]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
8. [8]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
9. [9]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
10. [10]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
11. [11]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
12. [12]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
13. [13]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
14. [14]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
15. [15]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
16. [16]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
17. [17]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
18. [18]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
19. [19]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
20. [20]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(366)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142