Citation: YAN Xiao-Ju, HE Huan, PENG Ying, WANG Xiao-Meng, GAO Zhan-Qi, YANG Shao-Gui, CHEN Hong-Zhe, SUN Cheng. Determination of Organophosphorus Flame Retardants in Surface Water by Solid Phase Extraction Coupled with Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1693-1697. doi: 10.3724/SP.J.1096.2012.20298 shu

Determination of Organophosphorus Flame Retardants in Surface Water by Solid Phase Extraction Coupled with Gas Chromatography-Mass Spectrometry

1.
School of the Environment, Nanjing University, State Key Laboratory of Pollution Control and Resources Reuse, Nanjing 210046, China

Corresponding author: CHEN Hong-Zhe, SUN Cheng,
Received Date: 23 March 2012
Available Online: 20 July 2012
Fund Project: 本文系国家自然科学基金(No.2127061) (No.2127061) 江苏省环境监测科研基金项目(No.1115) (No.1115)江苏省研究生创新计划(No.CXZZ11-0050)资助 (No.CXZZ11-0050)

Organophosphorus flame retardants (OPFRs), as their increasing production and consumption, are almost ubiquitous in environmental compartments. In this study, a solid phase extraction (SPE) coupled with gas chromatography-mass spectrometric (SPE-GC-MS) method was developed for the determination of 8 typical OPFRs. The targets in water samples were concentrated by Poly-Sery PSD SPE cartridge, and then eluted by 4 mL ethyl acetate. The OPFRs were qualified and quantified by GC-MS in selective ion scan monitoring method (SIM). Good linearity was observed in the range of 2 to 200 ng/L OPFRs with correlation coefficients varing between 0.9937 and 0.9995. The limits of detection and limits of quantification ranged from 0.006 to 0.850 ng/L and 0.015 to 2.000 ng/L, respectively. Spiked recoveries of pure water and river water samples ranged from 70.3% to 114.3%, with the relative standard deviations less than 15%, except for tri(2-ethylhexyl)phosphate(TEHP). The satisfied recovery of TEHP was achieved when the spiked concentration was less than 50 ng/L. The results showed that the SPE-GC-MS analytical method established was sensitive and accurate for the determination of OPFRs in surface water samples. Then the method was applied to analyze OPFRs in the water collected in Meiliang Bay of Taihu Lake, and it was found that the total concentration of OPFRs was ranging from 1000 to 2700 ng/L.
- Organophosphorus flame retardants,
- Solid phase extraction,
- Gas chromatography-mass spectrometry,
- Surface water
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沈阳化工大学材料科学与工程学院沈阳 110142