Citation: YANG Hui, ZHENG Lin-Ling, LI Yuan-Fang, HUANG Cheng-Zhi. Rhodamine Spirolactam and Copper Ion-based Fluorometric Detection of Phosphate in Artificial Wetlands[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1715-1719. doi: 10.3724/SP.J.1096.2012.20110 shu

Rhodamine Spirolactam and Copper Ion-based Fluorometric Detection of Phosphate in Artificial Wetlands

1.
¹ Education Ministry Key Laboratory on Luminescence and Real-Time Analysis, College of Chemical and Chemistry Engineering, Southwest University, Chongqing 400715, China;

Corresponding author: HUANG Cheng-Zhi,
Received Date: 10 February 2012
Available Online: 25 July 2012
Fund Project: 本文系国家自然科学基金(No. 21035005)资助 (No. 21035005)

Under neutral condition, phosphate ions could inhibit the catalytic effect of copper ions on the hydrolysis of rhodamine spirolactam to form fluorescent rhodamine B, resulting in the decrease of fluorescent intensity. Moreover, the inhibitive degree was in proportional to the concentration of phosphate ions, which could be developed for sensing phosphate. In the buffer (pH 7.0) solution, phosphate ions could be determined in the range of 3.0×10^-6-4.5×10^-5mol/L with the correlation coefficient of 0.9938 and the detection limit of 1.6×10^-7 mol/L (3σ). This method was applied to the detection of phosphate in artificial wetlands with the recovery from 93.0% to 108.0% and the RSD lower than 6.0%.
- Fluorometric method,
- Rhodamine spirolactam,
- Copper ions,
- Phosphate ions
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