Citation: ZHANG Ming, TANG Fang-Liang, FAN Xiao-Kai, XU Jian-Fen, CHEN Feng, WU Zhi-Xu. Determination of Three Amide Compounds in Environmental Water by Solid Phase Extraction Coupled with Hydrophilic Interaction Liquid Chromatography[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(10): 1555-1560. doi: 10.3724/SP.J.1096.2012.20064 shu

Determination of Three Amide Compounds in Environmental Water by Solid Phase Extraction Coupled with Hydrophilic Interaction Liquid Chromatography

1.
¹ Hangzhou Environmental Monitoring Central station, Hangzhou 310007, China;

Corresponding author: ZHANG Ming,
Received Date: 18 January 2012
Available Online: 25 April 2012
Fund Project: 本文系杭州市环境保护科技项目(No.2011003)资助 (No.2011003)

A simple hydrophilic interaction liquid chromatographic (HILIC) method for the determination of acrylamide (AA), N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMAC) in environmental water was developed. A cartridge containing graphitized carbon black was used for solid phase extraction (SPE) of the compounds in environmental water, the sample loaded was 1.0 mL, and then eluted with 1.0 mL acetonitrile, the elution was introduced into the instrument and determined by HPLC coupled with photo-diode array detector (PDA) at 200 nm. A good baseline separation of target compounds was obtained in 11 minutes under the optimum condition of determination. The calibration curves of 3 amides were linear in the concentration range of 0.05-100 mg/L with correlation coefficients of 0.9999. Overall recoveries were good (84.1%-106%), and the relative standard deviations ranged from 1.8% to 10.4% for the target compounds. The minimum detectable concentrations were 0.01 mg/L. This established method is convenient, sensitive and accurate, and was suitable for the routine detection of trace amide contaminants in environmental water.
- Hydrophilic interaction liquid chromatography,
- Solid phase extraction,
- Amide,
- Environmental water
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