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Citation: LUO Shixia, CHEN Xuan, ZHANG Xiaoyi, ZHU Huaiwu, WEI Gang. Synthesis,Ion recognition,and Extraction Properties of Propanedithioether Linked Bis-β-diketone Molecule[J]. Chinese Journal of Applied Chemistry, ;2014, 31(9): 1063-1068. doi: 10.3724/SP.J.1095.2014.40056 shu

Synthesis,Ion recognition,and Extraction Properties of Propanedithioether Linked Bis-β-diketone Molecule

LUO Shixia ^a,, ,
CHEN Xuan ^a ,
ZHANG Xiaoyi ^a ,
ZHU Huaiwu ^a ,
WEI Gang ^b,,

1.
a School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China;
2.
b CSIRO Materials Science and Engineering, PO Box 218, Lindfield, NSW 2070, Australia

Corresponding author: LUO Shixia, WEI Gang,
Received Date: 3 March 2014
Available Online: 14 May 2014
Fund Project: 教育部春晖计划合作科研资助项目(Z2008-1-55003) (Z2008-1-55003)

The bis-β-diketone molecule incorporating 1,3-propanedithioether bridge between the γ-carbons of respective β-diketone units of 1,3-bis(3-thio-2,4-pentanedionate) propane(L¹) was designed and synthesized via the Williamson reaction. The structure of bis-β-diketone L¹ was characterized by elemental analysis, ¹H NMR,¹³C NMR, MS, IR, UV and X-ray single crystal diffraction analysis. The analysis results show that the crystal of bis-β-diketone L¹ belongs to monoclinic, space group C2/c with cell parameters a=1.40679(9) nm, b=0.76521(5) nm, c=1.43213(10) nm, α=γ=90°, β=94.552°, V=1.53681(18) nm³, Z=4, Dc=1.316 g/cm³, μ=0.353 mm^-1, F(000)=648, and bis-β-diketone L¹ exists in the enol form in both solid state and chloroform solution. The recognition and extraction properties of the target compound L¹ with metal ions were investigated by the ultraviolet spectroscopy. The results show that bis-β-diketone L¹ has a good selective recognition and extraction property for Ni(Ⅱ) ion.
- bis-β-diketone,
- thioether,
- ion recognition,
- extraction properties
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