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Citation: WU Juan, GAO Bingying, HE Hongyun. Synthesis and Characterization of Heteroatomic Ti-Mn-β Zeolite and Its Catalytic Performance on Phenol Hydroxylation[J]. Chinese Journal of Applied Chemistry, ;2014, 31(11): 1302-1309. doi: 10.3724/SP.J.1095.2014.40029 shu

Synthesis and Characterization of Heteroatomic Ti-Mn-β Zeolite and Its Catalytic Performance on Phenol Hydroxylation

1.
College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China

Corresponding author: HE Hongyun,
Received Date: 23 January 2014
Available Online: 4 March 2014
Fund Project: 湖南省自然科学基金资助项目(08JJ3026) (08JJ3026)

Ti-Mn-β zeolite was hydrothermally synthesized in a SiO₂-SiO₂-MnO₂-(TEA)₂O-H₂O-NH₄F system.The structural characteristics of the products were determined by X-ray diffraction,infrared spectroscopy,UV-Vis diffuse reflectance spectroscopy,thermogravimetry-differential thermal analysis,scanning electron microscopy,and X-ray photoelectron spectroscopy.The factors affecting the synthesis of TiMn-β zeolite were investigated.The results show that the Ti-Mn-β zeolites have good catalytic activity in the hydroxylation of phenol with H2O2 as the oxidant.The phenol conversion is 29.8%,and the selectivities for catechnol and hydroquinone are 70.9% and 26%,respectively.
- Ti-Mn-β zeolite,
- hydrothermal synthesis,
- phenol hydroxylation
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