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Citation: SHA Sha, LI Jun, ZHUANG Changfu, LIU Shuxia, GAO Shuang. A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 799-805. doi: 10.3724/SP.J.1095.2014.30511 shu

A New Mesoporous Cobalt Metal-organic Framework was Synthesized by Post-functionalization and Its Application for the Epoxidation of Olefins

SHA Sha ^a,b ,
LI Jun ^b ,
ZHUANG Changfu ^b ,
LIU Shuxia ^a,, ,
GAO Shuang ^b,,

1.
a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, China;
2.
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: LIU Shuxia, GAO Shuang,
Received Date: 14 October 2013
Available Online: 14 October 2013
Fund Project: 中国博士后科学基金(2013M541257)资助项目 (2013M541257)

A newly Co²⁺ coordinated metal-organic framework had been successfully synthesized via one-step post-functionalization by hydrothermal method and characterized by Fourier transform infrared spectrometer,N₂ adsorption and inductively coupled plasma.Using O₂ as oxidant,mesoporous cobalt metal-organic framework was investigated as a heterogeneous catalytic material for the epoxidation of various olefins.Among them,the conversion of cyclooctene and the selectivity of epoxycyclooctane are 94% and 91%,respectively,and the turnover frequency is 509 h^-1.PCN-100(Co) exhibits excellent stabilities in 5 recycles without any loss of catalytic performance.
- metal-organic framework,
- post-functionalization,
- olefins epoxidation,
- molecular oxygen
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