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Citation: YAN Yin, LIU Ruiquan. Synthesis of Aryloxymethyl Imidazolinium Quaternary Ammonium Salt and Its Evaluation as A Corrosion Inhibitor[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 852-859. doi: 10.3724/SP.J.1095.2014.30504 shu

Synthesis of Aryloxymethyl Imidazolinium Quaternary Ammonium Salt and Its Evaluation as A Corrosion Inhibitor

YAN Yin ^a,, ,
LIU Ruiquan ^b

1.
a Department of Chemistry and Environmental Science, Kashgar Teachers' College, Kashgar 844000, China;
2.
b College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: YAN Yin,
Received Date: 11 October 2013
Available Online: 2 December 2013
Fund Project: 喀什师范学院青年教师专项课题[批准号(10)2360] (10)

Two aryloxymethyl imidazolinium quaternary ammonium salts(phenoxymethyl imidazolinyl quaternary ammonium salt(POAI) and naphthoxymethyl imidazolinyl quaternary ammonium salt(NOAI)) were synthesized.Their corrosion inhibition and adsorption behaviors on A₃ steel in 1 mol/L HCl solution were studied by mass loss and electrochemical techniques.The results show that the two compounds are good inhibitors for A₃ steel in 1 mol/L HCl,and they are mixed-type corrosion inhibitors.NOAI was found to have a superior inhibition efficiency to POAI.The inhibition efficiency increases with the concentration of inhibitor and the temperature.The experimental results reveal that the adsorption processes are endothermic and belong to the chemical adsorption.The adsorption characteristics of inhibitors are followed by the Langemuir isotherm.
- aryloxymethyl imidazolinium quaternary ammonium salt,
- corrosion inhibitor,
- A₃ steel
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