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Citation: WU Shengfu, HUANG Runjun, CHEN Donglian, HUANG Zengwei, MA Shaomei, YUAN Aiqun. Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 847-851. doi: 10.3724/SP.J.1095.2014.30501 shu

Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine

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a College of Preparatory Training Courses Education, Guangxi University For Nationalities, Nanning 530006, China;
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b Guilin University of Technology at Nanning, Nanning 530001, China;
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c College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China

Corresponding author: YUAN Aiqun,
Received Date: 9 October 2013
Available Online: 21 January 2014
Fund Project: 广西教育厅(200911MS99,200103YB041,2013YB105) (200911MS99,200103YB041,2013YB105)广西民族大学(2012MDZD042,2013MDYB028)资助项目 (2012MDZD042,2013MDYB028)

The intercalation reaction between aluminum dihydrogen tripolyphosphate(ATP) and organic amine such as methylamine,ethylamine,propylamine and butylamine were characterized by infrared,X-ray diffraction,scanning electron microscopy,energy disperses spectroscopy as well as gravitational thermal analysis and titration experiment.The results show that the organic amine is intercalated into the interlayer of ATP.The interlayer spacing of ATP is extended from 0.795 nm to 1.71 nm by intercalation of organic amine.The interlayer spacing of the intercalation compound is linear to the carbon number(C_n) of organic amine with d=0.229C_n+0.811 and R²=0.9986.Long molecule chains result in stripping tendency of the intercalation compounds.The acidity and thermal decomposition temperature of ATP are also changed after the intercalation of organic amine,but all layered particle morphologies are similar.
- aluminium dihydrogen triphosphate,
- organic amine,
- intercalation reaction,
- solid acid
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