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Citation: ZHANG Baohua, SHI Lanxiang. Asymmetric Henry Condensation Catalyzed by Ionic Liquid-supported Proline[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 812-816. doi: 10.3724/SP.J.1095.2014.30480 shu

Asymmetric Henry Condensation Catalyzed by Ionic Liquid-supported Proline

ZHANG Baohua ,
SHI Lanxiang ^,

1.
College of Chemical Engineering, Shijiazhuang University, Shijiazhaung 050035, China

Corresponding author: SHI Lanxiang,
Received Date: 24 September 2013
Available Online: 28 November 2013
Fund Project: 河北省科技支撑项目(13964002D) (13964002D)石家庄学院平台基金项目(XJPT007) (XJPT007)

A functionalized ionic liquid-supported proline,1-methyl-3-{2-[(2s)-pyrrolidine-2-carbonyloxy]-ethyl}-1H-imidazol-3-iumtrifluoroacetate([Promim]CF₃CO₂),was used to catalyze the Henry condensation reaction of aldehydes with CH₃CH₂NO₂ or CH₃NO₂.The desired products were obtained in 79%~95% yields,diastereomeric excess and enantiomeric excess was up to 3:1 and 85% under relatively mild conditions.[Promim]CF₃CO₂ could be efficiently recycled six times without the decrease of catalytic activity in the condensation reaction of 4-nitrobenzaldehyde and CH₃CH₂NO₂.
- ionic liquid-supported proline,
- Henry condensation,
- asymmetric catalysis
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