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Citation: LIU Lijun, CI Yingqian, WANG Qiliao, GONG Shuwen, CUI Qingxin. Selective Catalytic Nitration of Phenol to o-Nitrophenol by Silica Supported Cesium Salts of Molybdovanadophosphoric Acid[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 817-822. doi: 10.3724/SP.J.1095.2014.30463 shu

Selective Catalytic Nitration of Phenol to o-Nitrophenol by Silica Supported Cesium Salts of Molybdovanadophosphoric Acid

1.
Shandong Provincial Key Laboratory of Chemical Energy-Storge and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China

Corresponding author: GONG Shuwen,
Received Date: 16 September 2013
Available Online: 4 November 2013
Fund Project: 国家自然科学基金(21101086) (21101086)山东省优秀中青年科学家科研奖励基金(BS2010CL011)资助项目 (BS2010CL011)

A series of silica supported cesium salts of molybdovanadophosphoric acid catalysts with different loadings was prepared by sol-gel technology.Their properties were verified by XRD,IR spectra,SEM and physical adsorption technology.The catalytic activity of these catalysts was evaluated for the liquid phase nitration of phenol with dilute nitric acid under mild conditions.The effects of various parameters on the nitration were tested,which included reaction time,catalyst loading and reactants ratio.The results indicate that the catalyst prepared has the Keggin type structure and these particles are well dispersed on the surface of silica.The catalysts exhibit strong activity and high selectivity toward the o-nitration of phenol with a yield of 88% under appropriate conditions.Moreover,the supported catalysts can be recovered simply and reused several times.After the nitration,the o-nitrophenol obtained can be extracted via steam distillation.
- phenol,
- nitration,
- catalysis,
- o-nitrophenol
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