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Citation: LIU Liyan, SUN Yidan, YU Zhan, TIAN Peng, ZHANG Xiangdong, JIANG Lihong, LI Chengyu. Thermoluminescence of Rare Earth Ion Dy³⁺/Tm³⁺ Doped Zinc Tetraborate Phosphors[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 835-840. doi: 10.3724/SP.J.1095.2014.30461 shu

Thermoluminescence of Rare Earth Ion Dy³⁺/Tm³⁺ Doped Zinc Tetraborate Phosphors

1.
a School of Chemical and Life Sciences, Shenyang Normal University, Shenyang 110034, China;
2.
b School of Chemistry and Chemical Engineering, Liaoning University, Shenyang 110036, China;
3.
c Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: LIU Liyan,
Received Date: 12 September 2013
Available Online: 12 December 2013
Fund Project: 辽宁省教育厅科学研究一般项目(L2012393) (L2012393)沈阳师范大学优秀人才支持计划项目(2013年)资助 (2013年)

Dy³⁺ or Tm³⁺ doped zinc tetraborate(ZnB₄O₇) phosphors were prepared by the method of high temperature solid-state synthesis.The 3-dimensional thermoluminescent(TL) spectra of the phosphors after ⁶⁰Co γ-ray radiation were measured at room temperature.The 3-dimensional TL spectra show that the main TL glow peaks of these phosphors appear at about 218℃.3-Dimensional emission spectra of main TL peaks for the ZnB₄O₇:Tm³⁺ phosphor are at 366,453,475,651 and 754 nm,while TL peaks for the ZnB₄O₇:Dy³⁺ phosphor are at 480,573,665 and 755 nm,respectively.The formation of all peaks is ascribed to the characteristic rare earth ion transitions of Tm³⁺ and Dy³⁺ .The ZnB₄O₇:Tm³⁺ phosphor exhibits a higher TL emission efficiency,indicating its latent applicability in the field of radiation dosimetry compared with the ZnB₄O₇:Dy³⁺ phosphor.The kinetics parameters of the main TL peak of the ZnB₄O₇:Tm³⁺ phosphor at 218℃ were investigated by using the peak shape method.This peak shows the second-order kinetics while the trap depth(E) and the frequency factor are evaluated as 1.64 eV and 3.42×10¹⁶ s^-1,respectively.
- solid-state reaction,
- zinc tetraborate,
- rare earth,
- thermoluminescence
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Thermoluminescence of Rare Earth Ion Dy³⁺/Tm³⁺ Doped Zinc Tetraborate Phosphors