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Citation: WANG Hong, YANG Chi, XIE Wenfeng, YU Gang. A Polyolefin/Ceramic Composite Membrane for Lithium Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2014, 31(7): 757-762. doi: 10.3724/SP.J.1095.2014.30445 shu

A Polyolefin/Ceramic Composite Membrane for Lithium Ion Batteries

WANG Hong ^a,, ,
YANG Chi ^a ,
XIE Wenfeng ^b ,
YU Gang ^c

1.
a School of Chemistry and Chemical Engineering, Mianyang Normal University, Mianyang 621000, China;
2.
b Sichuan Normal University, Chengdu 610066, China;
3.
c Green Battery Co Ltd. Chongqing, 400708, China

Corresponding author: WANG Hong,
Received Date: 3 September 2013
Available Online: 4 November 2013
Fund Project: 四川教育厅基金项目(11ZA165) (11ZA165)绵阳师范学院支持项目(2011D01) (2011D01)

A polyolefin/ceramic composite membrane,ZrO₂/SiO₂/PP(PP:polypropylene),was prepared as the separator for Li-ion batteries in order to replace the traditional microporous polyolefin membrane.The polyolefin/ceramic composite membrane has high porosity,and can be well wetted by the liquid electrolyte.The ion conductivity of membrane is easily achieved by absorbing the liquid electrolyte due to the high capillary effect.The amphoteric character of ZrO₂/SiO₂ can scavenge acidic hydrogen fluoride,which is inevitably present in the LiPF₆-based electrolytes used currently in the Li-ion batteries.With the polyolefin/ceramic composite membrane as a separator,the graphite/cathode cell exhibits good capacity retention.It is also found that the Li-ion cell fabricated in this manner not only has stable capacity retention,better high temperature performance,but also shows good high-rate performance.
- polyolefin/ceramic composite membrane,
- Li-ion battery,
- ion conductivity,
- cycle life
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