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Citation: MUHAMMAD Kipayem, MUHAMMAD Turghun, TURAHUN Yunusjan, YAKUP Burabiye. Screening the Best Functional Monomer for Preparation of Molecularly Imprinted Polymer of 4-Nitrophenol and Its Application on Solid Phase Extraction of Water Sample[J]. Chinese Journal of Applied Chemistry, ;2014, 31(4): 474-481. doi: 10.3724/SP.J.1095.2014.30328 shu

Screening the Best Functional Monomer for Preparation of Molecularly Imprinted Polymer of 4-Nitrophenol and Its Application on Solid Phase Extraction of Water Sample

1.
College of Chemistry & Chemical Engineering, Xinjiang University, Key Laboratory of Oil and Gas Fine Chemicals, Educational Ministry of China, Urumqi 830046, China

Corresponding author: MUHAMMAD Turghun,
Received Date: 2 July 2013
Available Online: 26 August 2013
Fund Project: 新疆维吾尔自治区自然科学基金(2011211A015) (2011211A015)

A new method for rational design of molecularly imprinted polymer(MIP) of 4-nitrophenol(4-NP) was established.Using the method,nonimprinted polymer(NIP) library screening,vinylimidazole was selected as the best functional monomer.Acetonitrile and trimethylolpropane trimethacrylate(TRIM) were the best polymerization solvent and crosslinker,respectively.Through the optimization of the solid phase extraction(SPE) profile,the best imprinting effect was achieved in pH=2.5 phosphate buffer,washing with the buffer containing 45% acetonitrile and eluting with methanol.The maximum adsorption capacity of the polymer was 5.8 mg/g.Extraction recoveries of imprinted polymers for 4-NP and its analogs,phenol and 4-chlorophenol,were found to be 96.0%,78.8% and 77.8%,respectively,proving its high selectivity.It was also successfully used for SPE of 4-NP from spiked tap water with a recovery of 93.1%.The method is proved to be effective and fast for the preparation of MIPs.
- molecularly imprinted polymer,
- solid phase extraction,
- nitrophenol,
- monomer screening,
- dummytemplate
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Screening the Best Functional Monomer for Preparation of Molecularly Imprinted Polymer of 4-Nitrophenol and Its Application on Solid Phase Extraction of Water Sample

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com