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Citation: SU Ce, XIA Shujiao, CHANG Wenwu, HAN Lijuan. A New Cu(Ⅱ)-diamine Complex Catalyzed Henry Reaction[J]. Chinese Journal of Applied Chemistry, ;2014, 31(4): 411-416. doi: 10.3724/SP.J.1095.2014.30284 shu

A New Cu(Ⅱ)-diamine Complex Catalyzed Henry Reaction

1.
College of Petro-Chemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: SU Ce,
Received Date: 6 June 2013
Available Online: 16 September 2013
Fund Project: 兰州理工大学优秀青年教师计划项目(Q200912) (Q200912)

A new copper acetate complex derived from C₂-symmetric diamine,which can be easily prepared from L-proline,was developed and used as an efficient catalyst in Henry reaction between various aldehydes and nitroalkanes.The results demonstrate that the reaction temperature,solvents and catalyst loadings have considerably effects on both yields and reaction rates.The yields are 60%~92% in optimal reaction conditions:at room temperature,ethanol as solvent,10% molar fraction of catalyst loading.All aldehydes react efficiently with tested nitroalkanes to produce corresponding β-nitroalcohols.When aromatic aldehydes react with nitroethane,excellent diastereoselectivity can be obtained.However,diastereoselectivity is modest in the reaction of aliphatic acetaldehyde.
- Henry reaction,
- copper acetate,
- C₂-symmetric diamine,
- bidentate ligand
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