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Citation: WANG Fangxiao, ZHU Qiancheng, XIANG Dan, LIANG Lin, SUN Jianmin. Direct Oxidative Carboxylation of Styrene to Styrene Carbonate over Cobalt-containing Mesoporous Molecular Sieves(Co-MCM-41) and Tetrabutylammonium Bromide Co-catalysts[J]. Chinese Journal of Applied Chemistry, ;2014, 31(3): 268-273. doi: 10.3724/SP.J.1095.2014.30263 shu

Direct Oxidative Carboxylation of Styrene to Styrene Carbonate over Cobalt-containing Mesoporous Molecular Sieves(Co-MCM-41) and Tetrabutylammonium Bromide Co-catalysts

1.
a State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150080, China;
2.
b Natural Science Research Center, The Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin 150080, China;
3.
c School of Science, Xi'an Jiaotong University, Xi'an 710049, China;
4.
d School of Life Science and Technology, Harbin Institute of Technology, Harbin 150080, China

Corresponding author: SUN Jianmin,
Received Date: 24 May 2013
Available Online: 17 June 2013
Fund Project: 国家自然科学基金(21073049,21373069) (21073049,21373069)教育部新世纪人才(NCET-10-0064) (NCET-10-0064)哈尔滨工业大学城市水资源与水环境国家重点实验室基金项目(2013TS01)资助 (2013TS01)

Synthesis of cyclic carbonate from styrene and CO₂ gives a simple route that avoids the preliminary synthesis and isolation of epoxides.This direct synthesis route for cyclic carbonate from olefin is not only energy saving but also simple and economical.Herein,we synthesized various metal-dopped MCM-41 such as M-MCM-41(M=Co,Fe,Ni,Cu,Ti),and Co-MCM-41 catalyst showed the highest selectivity and yield to styrene epoxide among the various catalysts in the epoxidation of styrene.Then Co-MCM-41 was chosen to combine with tetrabutylammonium bromide(TBAB) to catalyze the direct oxidative carboxylation in one-pot.It was found that the Co-MCM-41/TBAB catalysts efficiently catalyzed the direct oxidative carboxylation of styrene to styrene carbonate.An improved styrene carbonate yield of 46.1% was obtained under mild reaction conditions of 80℃,7 h,and 4 MPa CO₂ pressure.It was found that Co-MCM-41 catalyzed the first epoxidation reaction and TBAB catalyzed the second cycloaddition reaction of CO₂.
- Co-MCM-41/tetrabutylammonium bromide,
- styrene,
- carbon dioxide,
- oxidative carboxylation,
- styrene carbonate
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