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Citation: SU Fansheng, SUN Yunming, LUO Xiaoyong, DONG Fengying, YANG Qing. Synthesis,Crystal and Molecular Structures and Herbicidal Activity of 2-(4-Methoxyphenyl) imidazole[4,5-f]1,10-phenanthroline[J]. Chinese Journal of Applied Chemistry, ;2014, 31(3): 290-295. doi: 10.3724/SP.J.1095.2014.30177 shu

Synthesis,Crystal and Molecular Structures and Herbicidal Activity of 2-(4-Methoxyphenyl) imidazole[4,5-f]1,10-phenanthroline

1.
a College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China;
2.
b College of Agronomy and Plant Protection, Qingdao Agricultural University, Qingdao 266109, China

Corresponding author: DONG Fengying,
Received Date: 12 April 2013
Available Online: 9 September 2013
Fund Project: 青岛农业大学高层次人才启动基金项目(630916) (630916)

2-(4-Methoxyphenyl) imidazole[4,5-f]1,10-phenanthroline was synthesized and characterized by FT-IR,elemental analysis and single crystal X-ray diffraction.The structure analysis revealed that each molecule formed two N——H…N hydrogen bonds with two adjacent molecules.Two types of π-π stacking modes were also observed in the title compound.N——H…N hydrogen bonds and π-π stacking interactions extend along the crystallographic c-axis and a-axis,respectively,which allows the title compound to assemble into a novel two-dimensional supramolecular architecture.The herbicidal activity of the title compound on Echinochloa crusgalli(L.) Beauv.,Lagopsis supine and Lactuca sativa were carried out by the method of grinded plant tissue powder mixed with agar(PPA).The results show that the growth of Echinochloa crusgalli(L.) Beauv.and Lagopsis supine is inhibited while the growth of Lactuca sativa is promoted by the title compound.
- synthesis,
- crystal structure,
- herbicidal activity,
- selectivity,
- plant growth regulator
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