Citation:
ZHENG Xi, CHEN Siying, CHEN Zhen, CHEN Riyao, CHEN Xiao. Preparation of Carbon-Coated TiO2-CeO2 Fibers for the Photocatalytic Degradation of Ciprofloxacin[J]. Chinese Journal of Applied Chemistry,
;2013, 30(11): 1326-1332.
doi:
10.3724/SP.J.1095.2013.30019
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The CeO2-TiO2 sol-gel was prepared by the sol-gel method using polyvinylpyrrolidone(PVP) sol/titaniumn-butyloxide (Ti(OC4H9)4) as the precursor and Ce(NO3)3·6H2O as the doping agent,and the CeO2 doped TiO2 nanofiber was prepared by the electrospinning technique. Finally,a layer of carbon membrane was deposited on the surface of the CeO2-TiO2 composite nanofibers using chemical vapor deposition(CVD). The structure and properties of the carbon-coated nanofibers were studied using SEM,FTIR,TEM,XRD,and its photocatalytic activity toward the degradation of ciprofloxacin hydrochloride was investigated under UV-light irradiation. The experimental results show that carbon-coated TiO2 composite nanofibers exhibit higher photocatalytic performance. When the irradiation time is 40 min,the degradation rate of ciprofloxacin hydrochloride is up to 85.8%.
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Keywords:
- electrospinning,
- TiO2,
- CeO2,
- carbon-coated,
- photocatalysis
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