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Citation: SHI Dongxin, CHEN Jiaojiao, DU Xianli, WANG Lele, JIANG Yi, REN Rongrong. Synthesis of Chiral Functional Monomers Containing L-Amino Acid Groups and Their Copolymers with N-Isopropylacrylamide[J]. Chinese Journal of Applied Chemistry, ;2013, 30(7): 740-744. doi: 10.3724/SP.J.1095.2013.20390 shu

Synthesis of Chiral Functional Monomers Containing L-Amino Acid Groups and Their Copolymers with N-Isopropylacrylamide

School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China

Received Date: 5 September 2012
Revised Date: 25 October 2012

Three chiral functional monomers containing L-phenylalanine(L-Phe),L-tryptophane(L-Trp) and L-leucine(L-Leu) were designed and synthesized and used as precursors for preparing of chiral polymers. After esterification and condensations,AAc-L-Phe(AAc:acrylic acid),AAc-L-Trp and AAc-L-Leu were obtained and characterized by IR and ¹H NMR. Then the subsequent copolymerization between AAc-L-Phe and N-isopropylacrylamide(NIPAam) was carried out in different mass ratio. The resulted polymers were identified by IR and differential scanning calorimetry(DSC) and proved that all of them are optical active and thermo-sensitive materials. The successful synthesis of chiral polymers suggested that these chiral monomers can be applied to the preparation of chiral polymers.
- chirality,
- L-amino acids,
- synthesis,
- functional monomers,
- copolymer
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