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Citation: WANG Lipin, WANG Senlin, DUAN Qianhua. Ni/NiFe₂O₄ Composite Electrode Prepared by Electro-deposition and Its Electro-catalytic Performance Towards Oxygen Evolution Reaction[J]. Chinese Journal of Applied Chemistry, ;2013, 30(6): 690-697. doi: 10.3724/SP.J.1095.2013.20385 shu

Ni/NiFe₂O₄ Composite Electrode Prepared by Electro-deposition and Its Electro-catalytic Performance Towards Oxygen Evolution Reaction

Department of Applied Chemistry, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

Received Date: 31 August 2012
Revised Date: 11 October 2012

The spinel-type NiFe₂O₄ powders have been synthesized by a hydroxide co-precipitation method. The Ni/NiFe₂O₄ composite coating was prepared through electro-deposition in Watt nickel plating by adding some NiFe₂O₄ powders. The optimized plating conditions for the composite electro-deposition were investigated by varying parameters,such as the plating solution pH and the cathode current density j_k. The composition and structure of the Ni/NiFe₂O₄ composite coating were characterized by scanning electron microscopy(SEM),energy X-ray diffraction(XRD) and dispersive spectrometer(EDS). The results show that the NiFe₂O₄ mass content in the Ni/NiFe₂O₄ composite coating is the highest(55.15%) at optimized plating conditions of a solution pH=5.8~6.0 and a cathodic current density j_k=40 × 10^-3~60 × 10^-3 A/cm². In 5 mol/L KOH solution,the electro-catalytic properties towards the oxygen evolution reaction(OER) of the Ni/NiFe₂O₄ composite electrode was studied using cyclic voltammetry,steady-state polarization,and chronoamperometry. Compared with the nickel electrode,the electro-catalytic properties towards OER of the Ni/NiFe₂O₄ electrode is higher and the apparent activation energy is decreased by 62.07 kJ/mol,and its specific surface area is 23.02 times as large as that of the nickel electrode. The constant-potential electrolysis with long time for OER shows that the stability of the Ni/NiFe₂O₄ composite electrode is good.
- composite electro-deposition,
- Ni/NiFe₂O₄,
- oxygen evolution reaction,
- electro-catalysis
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Ni/NiFe₂O₄ Composite Electrode Prepared by Electro-deposition and Its Electro-catalytic Performance Towards Oxygen Evolution Reaction