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Citation: WANG Wei, LIU Jingjing, ZHANG Long. Hydrogenation of Nitrobenzene to Aniline via a Hydrogen Transfer Process Catalyzed by Tris(acetylacetonato)ruthenium(Ⅲ)[J]. Chinese Journal of Applied Chemistry, ;2013, 30(4): 389-393. doi: 10.3724/SP.J.1095.2013.20372 shu

Hydrogenation of Nitrobenzene to Aniline via a Hydrogen Transfer Process Catalyzed by Tris(acetylacetonato)ruthenium(Ⅲ)

Jilin Provincial Engineering Laboratory for Complex Uitlization of Biomass and Petroresources, School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China

Received Date: 27 August 2012
Revised Date: 8 October 2012

Using home-made tris(acetylacetonato)ruthenium(Ⅲ),Ru(acac)₃,as catalyst,the hydrogenation of nitrobenzene to aniline via a hydrogen transfer process using sodium formate as hydrogen donor was investigated.The effects of reaction conditions such as temperature,time,dosage of catalyst and categories of hydrogen donor were investigated.The optimized reaction conditions are:the reaction temperature is 80℃,the reaction time is 4 h and the molar ratio of sodium formate to nitrobenzene is 2:1.Under optimized conditions,the conversion of nitrobenzene is nearly 100% with 96.65% yield of aniline.This result shows that Ru(acac)₃ exhibits good catalytic activities in the hydrogenation of nitrobenzene.
- tris(acetylacetonato) ruthenium(Ⅲ),
- catalytic transfer hydrogenation,
- nitrobenzene,
- aniline
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