Citation:
WANG Hong, ZHANG Weide. Surface-coating Modification of Li-rich Cathode Materials Li[Li0.2Mn0.4Fe0.4]O2[J]. Chinese Journal of Applied Chemistry,
;2013, 30(6): 705-709.
doi:
10.3724/SP.J.1095.2013.20364
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Li-rich cathode material of Li[Li0.2Mn0.4Fe0.4]O2 was prepared by co-precipitation,and was modified by surface coating with Al2O3. The modified samples were characterized by X-ray diffraction,scanning electron microscopy,and electrochemical tests. It was found that the 4.0% Al2O3 coated Li[Li0.2Mn0.4Fe0.4]O2 exhibited a good cycling performance compared with the bare Li[Li0.2Mn0.4Fe0.4]O2. The discharge capacity loss of the surface coated Li[Li0.2Mn0.4Fe0.4]O2 after 50 cycling was about 9%.
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