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Citation: WANG Hewen, FENG Yaqing, MENG Shuxian. Synthesis of Calix[4] arene Bonded with Coumarin-imino Units and Its Fluorescent Recognition of Metal Ions[J]. Chinese Journal of Applied Chemistry, ;2013, 30(3): 300-304. doi: 10.3724/SP.J.1095.2013.20190 shu

Synthesis of Calix[4] arene Bonded with Coumarin-imino Units and Its Fluorescent Recognition of Metal Ions

a. College of Chemical Engineering, Huanggang Normal University, Huanggang 438000, China;
b. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Received Date: 10 May 2012
Revised Date: 5 June 2012

A novel fluorescent calix[4] arene derivative(1) bonded with coumarin units as fluorophores and imino groups as ionophores was synthesized by condensation of 5,17-diaminocalix[4] arene with 7-hydroxy-4-methyl-2-oxo-2H-chromene-8-carbaldehyde. The structure of compound 1 was fully characterized by IR,¹H NMR,¹³C NMR and MS. The recognition properties of compound 1 toward transition and heavy metal ions were studied by UV-Vis and fluorescent spectroscopies. The results show that compound 1 can selectively recognize Fe³⁺ and Cr³⁺ ions. The complexation ratio of compound 1 with Fe³⁺or Cr³⁺ is 1:1. The association constants of compound 1 with Fe³⁺ and Cr³⁺ were 4.1 × 10⁵ and 1.07 × 10⁵ L/mol,respectively.
- aminocalixarene,
- coumarin-imino fluorescent reagent,
- synthesis,
- fluorescent recognition
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