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Citation: YANG Jiandong, WANG Duliu, LU Xiaoquan. Preparation and Characterization of Different Self-Assembled Porphyrin Monolayers[J]. Chinese Journal of Applied Chemistry, ;2013, 30(3): 343-348. doi: 10.3724/SP.J.1095.2013.20109 shu

Preparation and Characterization of Different Self-Assembled Porphyrin Monolayers

a. Department of Biology & Chemistry, Longnan Normal College, Chengxian 742500, China;
b. Key Laboratory of Bioelectrochemisty & Environmental Analysis of Gansu Province, Northwest Normal of University, Lanzhou 730070, China

Received Date: 22 March 2012
Revised Date: 31 May 2012

Different self-assembled thiol-substituted porphyrin monolayers (TPPS₁ and TPPS₄) were prepared and characterized by means of UV-Vis,CV,EIS and XPS.The results showed that the self-assembled porphyrin monolayers have different configurations due to the different numbers of the thiol-substitute in porphyrin molecules.Therefore,these porphyrin monolayers showed different performance in catalysis.On the basis of those observations,we proposed a model for the assembling of multi-thiol substituted porphyrin into monolayer.The established method shows potential for building and developing functional self-assembled porphyrin monolayers in the application of bio-catalysis and optoelectronic devices.
- multi-thiol substituted porphyrin compounds,
- self-assembled monolayer,
- preparation and characterization,
- model
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