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Citation: YUAN Donghai, TANG Anbin, HUANG Jie, MA Hanbing. Synthesis of Hexaphenoxycyclotriphosphazene with Allyl Group and Application in Flame Retardant Acrylate Resin[J]. Chinese Journal of Applied Chemistry, ;2012, 29(9): 1090-1092. doi: 10.3724/SP.J.1095.2012.00464 shu

Synthesis of Hexaphenoxycyclotriphosphazene with Allyl Group and Application in Flame Retardant Acrylate Resin

YUAN Donghai ^a ,
TANG Anbin ^a,b,, ,
HUANG Jie ^b ,
MA Hanbing ^a

1.
a School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
2.
b Sichuan EM Technology Co. Ltd., National Insulating Material Engineering Research Center, Mianyang 621000, China

Corresponding author: TANG Anbin,
Received Date: 21 October 2011
Available Online: 12 January 2012
Fund Project: 十一五国家科技支撑计划项目(2007BAE50B03) (2007BAE50B03)四川省青年科技基金资助项目(08JJ0100) (08JJ0100)

A novel cyclophosphazene flame retardant monomer with allyl group,2-allyl phenoxy-pentaphenoxycyclotriphosphazene(APPCP),was synthesized by using hexachlorocyclotriphosphazene(HCCP),2-allylphenol and phenol as the starting materials.The structure of the product was characterized by FTIR,MS,¹H NMR and elemental analysis.The flame retardant acrylate resin was prepared through copolymerized with APPCP and acrylate resin monomers,and the effects of APPCP on the thermal and flame-retardant properties were investigated.With the addition of 20%APPCP,the flammability class of the copolymerized acrylate resin was attained to V-0,with the limiting oxygen index(LOI) value increased to 31.2%,and the residual mass up to 23.2% at 600℃.
- cyclotriphosphazene,
- flame retardant,
- acrylate,
- copolymerization
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