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Citation: BAI Ling, XIAO Ge, ZHUO Guanglan. Asymmetric Synthesis of(S)-3-Chloro-1-phenyl-1-propanol Using Borane Amine Complex-CBS as Catalyst[J]. Chinese Journal of Applied Chemistry, ;2012, 29(9): 1087-1089. doi: 10.3724/SP.J.1095.2012.00451 shu

Asymmetric Synthesis of(S)-3-Chloro-1-phenyl-1-propanol Using Borane Amine Complex-CBS as Catalyst

1.
Department of Chemistry, Zhejiang Science-Technique University, Hangzhou 310018, China

Corresponding author: ZHUO Guanglan,
Received Date: 8 October 2011
Available Online: 20 January 2012

(S)-3-Chloro-1-phenyl-1-propanol was synthesized asymmetrically by using catalysts(R)-α,α-diphenyl-2-pyrrolidinemethanol,(1R,2S)-2-amino-1,2-diphenylethanol and(1R,2R)-1-amino-2-indanol with amine borane complexes,with a yield of 88.3%~93.8%,ee% 81.6~87.7.These amine borane complexes are more stable and safe than the borane-tetrahydrofuran complex and borane-methyl sulfide complex.
- borane amine complex,
- CBS catalyst,
- (S)-chlorophenylpropanol,
- fluoxetine
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