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Citation: YU Tao, LUO Shiqiong, DING Wei, WANG Huimin, YUAN Dandan, QU Guangmiao, LI Zhong. Effect of the Structure of Alkyl Aryl Sulfonates on the Microemulsive Phase Behavior[J]. Chinese Journal of Applied Chemistry, ;2012, 29(9): 1060-1064. doi: 10.3724/SP.J.1095.2012.00421 shu

Effect of the Structure of Alkyl Aryl Sulfonates on the Microemulsive Phase Behavior

YU Tao ^a,, ,
LUO Shiqiong ^a ,
DING Wei ^a ,
WANG Huimin ^a ,
YUAN Dandan ^a ,
QU Guangmiao ^a ,
LI Zhong ^b

1.
a College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2.
b Linpan Drilling Company, Sinopec China Southwest Petroleum Bureau, Dezhou 253000, China

Corresponding author: YU Tao,
Received Date: 20 September 2011
Available Online: 1 December 2011
Fund Project: 国家重点基础研究发展规划"973"项目(2005CB221300)资助 (2005CB221300)黑龙江省研究生创新科研项目(YJSCX2008-044HLJ)资助 (YJSCX2008-044HLJ)

The complex system of six kinds of different structure of alkyl aryl sulfonates(synthesized in the laboratory)/different alchol/n-decane/NaCl water microemulsions were investigated by Winsor phase diagram.The effects of molecular structure,temperature and alcohol were invetigated.The results showed that as the number of long alkyl carbon atoms in alkyl aryl sulfonate molecule increase,the values of S₁,S₂(the salt concentrations of middle-phase microemulsion appears or disappears),ΔS(salt concentration width) and S^*(optimal concentration of salt) decrease,while the values of V_M^*(optimal volume of middle-phase microemulsion) and σ^*(σ^* means optimal solubilization) increase.Similar trends were also observed with the increase of temperature and carbon atom numbers of the alcohols and no middle phase microemulsion could be formed at 25℃.However,as the aromatic rings shift from the edge to the middle of the long carbonic chains,the values of S₁,S₂ and ΔS,S^* decrease and those of V_M^* and σ^* increase.
- alkyl aryl sulfonate,
- microemulsion,
- phase behavior,
- Winsor phase diagram
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