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Citation: BAI Qinglong, ZHANG Chunhua, CHENG Chuanhui, LI Wancheng, DU Guotong. Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc[J]. Chinese Journal of Applied Chemistry, ;2012, 29(6): 643-648. doi: 10.3724/SP.J.1095.2012.00271 shu

Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc

1.
a College of Chemistry and Chemical Engineering, Inner Mongglia University for Nationalities, Tongliao 028043, China;
2.
b School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, China;
3.
c College of Electronic Science and Engineering, Jilin University, Changchun 130012, China

Corresponding author: CHENG Chuanhui,
Received Date: 22 June 2011
Available Online: 25 September 2011
Fund Project: 国家自然科学基金(60807009)资助项目 (60807009)

α(β)-tetra-phenoxy phthalocyaninato zinc complexes have been synthesized via a two-step process using 3(4)-nitrobenzene-1,2-dicarbonitrile and phenol as precursors.The products were characterized by means of IR spectrum,UV-Vis spectrum,¹H NMR spectrum,mass spectrum and elemental analysis.The UV-Vis spectra,photoluminescence spectra of spin-coated film and pressed solid pellet were compared.The fluorescences of both compressed and spin-coated samples had red-shifts larger than 161 nm compared to that obtained from solution.In addition,their fluorescence peaks are broader than that in solution.The fluorescence of β-substituted phthalocyanines has a greater red-shift than that of α-substituted phthalocyanines.The two kinds of fabricated devices showed similar electroluminescent spectra around 880 nm.
- phenoxy phthalocyaninato zinc,
- synthesis,
- photoluminescence,
- electroluminescence,
- red-shift
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