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Citation: ZHANG Peipei, WANG Aijun, LIU Xueyan, ZHU Hongqiao, DU Junfang, CHEN Xuan, FENG Jiuju. Layer-by-layer Self-assembled Prussian Blue Modified Electrode and Its Application for the Detection of Hydrogen Peroxide[J]. Chinese Journal of Applied Chemistry, ;2012, 29(5): 585-590. doi: 10.3724/SP.J.1095.2012.00268 shu

Layer-by-layer Self-assembled Prussian Blue Modified Electrode and Its Application for the Detection of Hydrogen Peroxide

1.
Key Laboratory of Green Chemical Media and Reactions, Ministry of Education;School of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China

Corresponding author: FENG Jiuju,
Received Date: 21 June 2011
Available Online: 19 September 2011
Fund Project: 国家自然科学基金(20805011,20905021)资助项目 (20805011,20905021)

Para aminobenzene sulfonic acid(p-ABSA) was deposited onto the surface of a glass carbon electrode(GCE) through the electrochemical deposition.Cation-exchange properties of the deposited p-ABSA were then employed to confine ferric ion(Fe³⁺) within the polymeric layer.Ferrocyanide ions([Fe(CN)₆]^4-) can react with the adsorbed Fe³⁺ forming Prussian blue(PB).PB crystals were formed by alternative adsorption of Fe³⁺ and reaction with[Fe(CN)₆]^4-.The crystal shows high catalytic activity toward the electrochemical reduction of hydrogen peroxide.Cyclic voltammetry,electrochemical impedance spectroscopy and typical amperometric response method were employed to characterize the electrochemical properties of the PB modified electrode.The experimental parameters(applied potential,pH,and interfering substances) influencing the performance of the PB modified electrode were investigated in details.Under optimal conditions,the PB modified electrode exhibits a wider linear range of 0.97~32.33 mmol/L with the fast response less than 5 s and a low detection limit of 0.48 mmol/L(S/N=3).
- Prussian blue,
- p-aminobenzene sulfonic acid,
- ferric ion,
- ferrocyanide,
- hydrogen peroxide
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