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Citation: CHENG Chuanjie, ZHA Jiwei, LIU Zhongbin, SHEN Liang, SUN Jian, LIU Yingjia. Synthesis and UV Curing Properties of a Photo-active Cardanol Derivative[J]. Chinese Journal of Applied Chemistry, ;2012, 29(4): 392-396. doi: 10.3724/SP.J.1095.2012.00254 shu

Synthesis and UV Curing Properties of a Photo-active Cardanol Derivative

1.
School of Chemistry and Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 330013, China

Corresponding author: SHEN Liang,
Received Date: 14 June 2011
Available Online: 21 July 2011
Fund Project: 国家自然科学基金(51063002) (51063002)江西省自然科学基金(2009GZH0035) (2009GZH0035)

A cardanol derivative(1) with photo-initiating activity has been synthesized in 86% yield using cardanol and 4-bromomethyl benzophenone as precursors.The photo-initiating performance of the derivative 1 is better than common benzophenone according to the results of the controlled experiments.The derivative 1 can be completely cured within 30 s under UV irradiation without the presence of any photoinitiator.Furthermore,the mixtures of the derivative 1 and cardanol with various ratios can also be cured under UV irradiation that the UV-curing time is prolonged up to dozens of minutes with the increase of cardanol content.The resulting cured films show relatively high hardness(3H-5H),excellent solvent,acid and base resistance,which have potential application in anti-corrosion coatings.
- cardanol,
- bromomethyl benzophenone,
- UV-curing,
- photo-initiating,
- anti-corrosion coatings
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