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Citation: CHEN Shikun, ZHAO Xianghua, WU Jieying, TIAN Yupeng. Synthesis, Crystal Structure and Fluorescent Property of β-Diketone and Triphenylphosphine Copper(Ⅰ) Mixed-Ligand Complex[J]. Chinese Journal of Applied Chemistry, ;2012, 29(3): 280-284. doi: 10.3724/SP.J.1095.2012.00194 shu

Synthesis, Crystal Structure and Fluorescent Property of β-Diketone and Triphenylphosphine Copper(Ⅰ) Mixed-Ligand Complex

1.
a Faculty of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China;
2.
b Department of Chemistry and Chemical Engineering, Huainan Normal University, Huainan 232001, China

Corresponding author: TIAN Yupeng,
Received Date: 10 May 2011
Available Online: 14 July 2011
Fund Project: 国家自然科学基金(21071001)资助项目 (21071001)安徽省教育厅自然科学基金重点项目(KJ2010A030) (KJ2010A030)

A β-diketone ligand L(3-(4,4,4-trifluorobutane-1,3-diketone)-9-butylcarbazole) was synthesized according to literature method.The copper(Ⅰ) complex with fluorescent activity was prepared by the reaction of copper nitrate,copper,triphenylphosphine and L,which was characterized by elemental analysis and IR spectra.Its crystal structure was determined by single crystal X-ray diffraction analysis.The crystal belongs to monoclinic,P2₁/c space group.Cell parameters:a=1.6428(5) nm,b=1.0434(5) nm,c=2.8001(5) nm,V=4.800(3) nm³,Z=4,D_c=1.313 Mg/m³,R[I>2σ(I)] R₁=0.0501,wR₂=0.0808.The Cu(Ⅰ) ion in the distorted tetrahedral copper(Ⅰ) complex is coordinated by two O atoms from the two β-diketone ligands,and two P atoms from triphenylphosphine,respectively.Fluorescent properties of the copper(Ⅰ) complex were studied,which indicated that the complex had strong fluorescent emission in dichloromethane solution.
- trifluorobutane-diketone-butylcarbazole,
- copper(Ⅰ) complex,
- crystal structure
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