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Citation: ZHANG Yanmei, DUAN Chengqian, GAO Zuoning. Electrocatalytic Oxidation of Bisphenol A at SDS Selfassembled Monolayer and[Bupy]PF₆ Modified Carbon Paste Electrode and Its Electrochemical Determination[J]. Chinese Journal of Applied Chemistry, ;2012, 29(3): 353-358. doi: 10.3724/SP.J.1095.2012.00164 shu

Electrocatalytic Oxidation of Bisphenol A at SDS Selfassembled Monolayer and[Bupy]PF₆ Modified Carbon Paste Electrode and Its Electrochemical Determination

1.
a Key Laboratory of Energy Sources and Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China;
2.
b Chemical Teaching and Research Section of Higher Vocational College, Ningxia Medical University, Yinchuan 750004, China

Corresponding author: GAO Zuoning,
Received Date: 21 April 2011
Available Online: 18 July 2011

The electrocatalytic oxidation and electrochemical kinetics of bisphenol A(BPA) were investigated at sodium dodecyl sulphate(SDS) self-assembled monolayer and N-butylpyridinium hexafluorophosphate(PF₆) modified carbon paste electrode(CPE).The experimental results indicated that BPA electrochemical behavior exhibited an irreversible electrochemical oxidation process at SDS-PF₆/CPE.The electrochemical kinetic parameters were determined by cyclic voltammetry(CV),chronoamperometry(CA).The oxidation peak current of BPA had a good linear relationship with the concentration of BPA in the range of 1.0×10^-5~1.0×10^-3 mol/L with a correlation coefficient of 0.9981,and a detection limit of 3.01×10^-7 mol/L(S/N=3) was obtained by square wave voltammetry(SWV).The method was applied to determine quantitative BPA content in lake water samples with satisfactory results.
- bisphenol A,
- sodium dodecyl sulphate,
- N-butylpyridinium hexafluorophosphate,
- carbon paste electrode,
- electrocatalytic oxidation
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Electrocatalytic Oxidation of Bisphenol A at SDS Selfassembled Monolayer and[Bupy]PF6 Modified Carbon Paste Electrode and Its Electrochemical Determination

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通讯作者: 陈斌, bchen63@163.com

Electrocatalytic Oxidation of Bisphenol A at SDS Selfassembled Monolayer and[Bupy]PF₆ Modified Carbon Paste Electrode and Its Electrochemical Determination