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Citation: LIU Caisheng, QIAO Haiyan, GU Ningyu, TANG Jilin. Determination of Hydrogen Peroxide Using 4-(2-Pyridylazo)-Resorcinol Polymer Film Modified Glassy Carbon Electrode[J]. Chinese Journal of Applied Chemistry, ;2012, 29(2): 216-221. doi: 10.3724/SP.J.1095.2012.00110 shu

Determination of Hydrogen Peroxide Using 4-(2-Pyridylazo)-Resorcinol Polymer Film Modified Glassy Carbon Electrode

LIU Caisheng ^a ,
QIAO Haiyan ^b ,
GU Ningyu ^a,, ,
TANG Jilin ^b,,

1.
a Department of Chemistry, Nanchang University, Nanchang 330031, China;
2.
b State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: GU Ningyu, TANG Jilin,
Received Date: 17 March 2011
Available Online: 4 May 2011
Fund Project: 江西省科技支撑项目(2010BGB01001)资助 (2010BGB01001)

A sensor for determination of hydrogen peroxide(H₂O₂) based on 4-(2-pyridylazo)-resorcinol(PAR) polymer film modified glassy carbon electrodes(GCE) was fabricated.Electrochemical properties and characteristics of the PAR polymer film modified electrode for H₂O₂ reduction were investigated using cyclic voltammetry and chronoamperometry methods.The results showed that the modified electrode exhibited good electrocatalytic activity towards the reduction of H₂O₂ at a low potential.The chronoamperometric detection of H₂O₂ was carried out at-0.45 V in 0.1 mol/L phosphate buffered solution(pH=8.0).The peak currents of H₂O₂ reduction varied linearly with the concentration in the range of 2×10^-5~1.76×10^-3 mol/L,with a linearly dependent coefficient r=-0.99983,the detection limit(S/N=3) was 3 μmol/L.The modified electrode showed high sensitivity,good stability,easy preparation and exhibited better anti-interference to ascorbic acid,uric acid and glucose.
- (pyridylazo)-resorcinol,
- hydrogen peroxide,
- cyclic voltammetry,
- chronoamperometry
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