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Citation: YIN Jishen, JIA Lihua, GUO Xiangfeng, ZHANG Xueju. Catalytic Hydroxylation of Benzene to Phenol with Vanadium Containing Hexagonal Mesoporous Silica[J]. Chinese Journal of Applied Chemistry, ;2012, 29(1): 57-62. doi: 10.3724/SP.J.1095.2012.00076 shu

Catalytic Hydroxylation of Benzene to Phenol with Vanadium Containing Hexagonal Mesoporous Silica

1.
College of Chemistry and Chemical Engineering of Qiqihar University, Qiqihar 161006, China

Corresponding author: JIA Lihua,
Received Date: 24 February 2011
Available Online: 7 June 2011
Fund Project: 黑龙江省博士后科研启动项目(LBH-Q07118) (LBH-Q07118)齐齐哈尔大学研究生创新项目(YJSCX2010-024X) (YJSCX2010-024X)

Vanadium containing hexagonal mesoporous silica(V-HMS) catalysts with different vanadium contents were prepared by sol-gel method with ammonium metavanadate used as the starting material of vanadium,and the obtained catalysts were characterized by powder X-ray diffraction(XRD),N₂-adsorption techniques and H₂-temperature programmed reduction(H₂-TPR).The catalytic performance for hydroxylation of benzene with H₂O₂ to phenol was investigated.The results indicated that vanadium species was successfully incorporated into the framework of HMS,and a uniform mesoporous structure and good dispersion were found.Meanwhile,V-HMS exhibited superior catalytic performance in the hydroxylation of benzene to phenol.The good dispersion and isolated vanadium species were beneficial to the high catalytic activity of hydroxylation of benzene to phenol.When the mass fraction of V(5.8% mass fraction)-HMS was 2%,the reaction temperature was 60℃,and the reaction time was 5 h,the yield and selectivity of phenol achieved 18.55% and 100%,respectively.
- vanadium,
- hexagonal mesoporous silica,
- benzene,
- hydroxylation,
- phenol
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