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Citation: TANG Huaijun, ZHANG Meifang, ZHANG Zhiguo, SHI Qing, ZHANG Keli. Synthesis and Characterization of Two β-Diketones with Carbazole Group[J]. Chinese Journal of Applied Chemistry, ;2011, 28(11): 1239-1243. doi: 10.3724/SP.J.1095.2011.00675 shu

Synthesis and Characterization of Two β-Diketones with Carbazole Group

TANG Huaijun ^a,b,, ,
ZHANG Meifang ^b ,
ZHANG Zhiguo ^b ,
SHI Qing ^b ,
ZHANG Keli ^b,,

1.
a Institute of Polymer Optoelectronic Materials and Devices, Key Lab of Specially Functional Materials of the Ministry of Education, South China University of Technology, Guangzhou 510640;
2.
b College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072

Corresponding author: TANG Huaijun, ZHANG Keli,
Received Date: 15 November 2010
Available Online: 13 January 2011
Fund Project: 国家自然科学基金(20071026) (20071026)中国博士后科学基金(20090450858)资助项目 (20090450858)

Two β-diketones with carbazole group were synthesized from carbazole and biphenyl. The β-diketones were characterized by ¹H NMR, ¹³C NMR, MS, elemental analyses, thermoanalysis, UV-Vis absorption spectra and photoluminescence(PL) spectra. The β-diketones have high thermal stability, their 5% mass-reduction temperatures(ΔT_5%) are 319℃ and 356℃, respectively. Their PL spectra lie in blue light zone with the maximum emission peaks of 443 nm and 455 nm. They are potential ligands for synthesizing metal ion complexes targeted for light-emitting materials.
- β-diketones,
- carbazole,
- biphenyl,
- Claisen condensation
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