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Citation: ZENG Zhi, XIE Runqian, TAN Lixian, ZHANG Tao. GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 956-962. doi: 10.3724/SP.J.1095.2011.00598 shu

GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction

ZENG Zhi ^a,b,, ,
XIE Runqian ^a ,
TAN Lixian ^a ,
ZHANG Tao ^c

1.
a School of Chemistry and Environment, South China Normal University, Guangzhou 510631;
2.
b Faculty of Bioresource Sciences, Akita Prefectural University, Akita 010-0195, Japan;
3.
c Institute of Opto-electronic Materials and Technology, South China Normal University, Guangzhou 510631

Corresponding author: ZENG Zhi,
Received Date: 11 October 2010
Available Online: 28 December 2010
Fund Project: 广东省科技计划重大专项(A301020101) (A301020101)广东省自然科学基金(01142)资助项目 (01142)

The chemical components of Ligusticum chuanxiong Hort.were extracted by steam distillation and supercritical CO₂ extraction,and analyzed by combined capillary gas chromatography-mass spectrometry(GCMS).Thirty and thirty four compounds were identified,respectively,and their relative contents were determined.This study revealed that the major components of L.chuanxiong Hort.by steam distillation and supercritical CO₂ extraction were(Z)-ligustilide.The chemical components from L.chuanxiong Hort.extracted by supercritical CO₂ extraction possessed more bioactive substances such as butylphthalide,butylidene phthalide,senkyunolide A,(Z)-ligustilide,(E)-ligustilide and senkyunolide I.However,the components from L.chuanxiong Hort.extracted by steam distillation contained more terpenes except for the bioactive substances.Therefore,supercritical CO₂ extraction has more productivity than steam distillation for the extraction of the bioactive substances from L.chuanxiong Hort.Through the interpretation and summarization of the regular patterns of the lactones with unsaturated and saturated side chains from L.chuanxiong Hort.,the structures of the lactones with unsaturated side chain such as(Z)-ligustilide,(E)-ligustilide,butylidene phthalide and senkyunolide I as well as the lactones with saturated side chain such as butylphthalide and senkyunolide A have been determined.
- Ligusticum chuanxiong Hort.,
- steam distillation,
- supercritical CO₂ extraction,
- mass spectrometry,
- chemical component,
- structure determination
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GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO2 Extraction

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GC-MS Analysis and Determination of Chemical Components of the Extracts from Ligusticum Chuanxiong Hort.by Steam Distillation and Supercritical CO₂ Extraction