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Citation: YU Hongwei, GUAN Min, TONG Qingsong, JIA Li, JIN Zilin, SHI Jicheng. Synthesis and Enhanced Activity of Etherlized Ferrocenylphosphine for the PalladiumCatalyzed Suzuki Reaction[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 887-891. doi: 10.3724/SP.J.1095.2011.00541 shu

Synthesis and Enhanced Activity of Etherlized Ferrocenylphosphine for the PalladiumCatalyzed Suzuki Reaction

YU Hongwei ^b,c ,
GUAN Min ^b ,
TONG Qingsong ^a ,
JIA Li ^a ,
JIN Zilin ^b ,
SHI Jicheng ^a,,

1.
a College of Chemistry and Materials Science, Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007;
2.
b State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian;
3.
c School of Chemical Engineering, Shijiazhuang College, Shijiazhuang

Corresponding author: SHI Jicheng,
Received Date: 15 September 2010
Available Online: 28 December 2010
Fund Project: 国家自然科学基金(20971023) (20971023)福建省自然科学基金(2007J0306)资助项目 (2007J0306)

A new etherlized ferrocenylphosphine ligand,2-diphenylphosphino-ferrocenyl-ethyl-5-hydroxyl-3-oxo-pentyl ether,was prepared by the reaction of acetyl 1-(diphenylphosphinoferrocenyl) ethyl ester with diethylene glycol in 77% yield.Its structure was characterized by ¹H NMR,¹³C NMR,³¹P NMR and MS.The synthesized ferrocenylphosphine has been applied as supporting ligand in the palladium-catalyzed Suzuki reaction;its ligated palladium catalyst is effective for coupling a range of aryl bromides as well as aryl chlorides having electron-withdrawing groups with phenylboronic acid to prepare the corresponding biaryls.The possible coordination of ether-oxygen to the Pd center may enhance the catalytic performance of the ligand for cross-coupling reaction.
- ferrocenylphosphine,
- etherlization,
- palladium,
- Suzuki reaction,
- biaryl
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