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Citation: DING Wei, REN Ya'ni, LIU Hongbin, SHI Peng, YU Tao, QU Guangmiao, CHENG Jiecheng, WU Junzheng. Effect of Relative Molecular Mass on the Adsorption of Alkyl Aryl Sulfonate Composite Systems at the Solid-Liquid Interface[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 963-968. doi: 10.3724/SP.J.1095.2011.00526 shu

Effect of Relative Molecular Mass on the Adsorption of Alkyl Aryl Sulfonate Composite Systems at the Solid-Liquid Interface

DING Wei ^a,, ,
REN Ya'ni ^′a ,
LIU Hongbin ^a ,
SHI Peng ^a ,
YU Tao ^a ,
QU Guangmiao ^a ,
CHENG Jiecheng ^b ,
WU Junzheng ^b

1.
a Oil and Gas Provincial Key Laboratory, Chemistry and Chemical Engineering College, Northeast Petroleum University, Daqing, 163318;
2.
b Development Department of Science and Technology, Daqing Oil Field Company Limited, Daqing

Corresponding author: DING Wei,
Received Date: 7 September 2010
Available Online: 29 October 2010
Fund Project: 国家重点基础研究发展规划“九七三”资助项目(2005cb221300) (2005cb221300)

The isotherms and the adsorption amount of alkyl aryl sulfonates with five types of relative molecular mass(M_r) distribution were measured on the solid-liquid interface.The impacts of M_r,M_r distribution,adsorption temperature,and the inorganic salt on the adsorption of alkyl aryl sulfonate compounds on the oil sand/quartz sand surface were discussed,respectively.The results showed that the adsorption amount of the five types of alkyl aryl sulfonate compounds were decreased in the following order:the incremental distribution,normal distribution,reverse normal distribution,descending distribution,uniform distribution;while the adsorption amount of alkyl aryl sulfonate compounds on the oil sands surface increased with the increase of their M_r and the NaCl concentration,and decreased with the increase of the adsorption temperature.The effect of NaCl on the adsorption of the alkyl aryl sulfonate compounds on the oil sands surface was slightly greater than that on the quartz sands surface.Moreover,it was found that CaCl₂,MgCl₂,Na₂ SO₄ etc.have a more significant effect on the adsorption amount than NaCl.
- alkyl aryl sulfonates,
- composite system,
- solid-liquid adsorption,
- oil sands,
- quartz sands,
- inorganic salt
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