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Citation: HUANG Xueliang, ZHU Fanghua, YANG Junxiao, ZHANG Lin. Synthesis and Properties of Diethyl Tetramethyl Disiloxane Bisbenzocyclobutene and Its Polymer[J]. Chinese Journal of Applied Chemistry, ;2011, 28(6): 640-644. doi: 10.3724/SP.J.1095.2011.00425 shu

Synthesis and Properties of Diethyl Tetramethyl Disiloxane Bisbenzocyclobutene and Its Polymer

1.
a School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang;
2.
b Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900

Corresponding author: ZHANG Lin,
Received Date: 22 July 2010
Available Online: 27 October 2010
Fund Project: 国家高技术研究发展计划项目"八六三"基金资助项目(2009AA8-441011) (2009AA8-441011)

Hydrosilylation reaction of 4-vinylbenzocyclobutene(4-VBCB) with 1,1,3,3-tetramethyl-1,3-dihydro disiloxane(TMHS) was employed to afford the monomer of diethyl tetramethyl disiloxanebisbenzocyclobutene(DES-bis-BCB).The structures of DES-bis-BCB and the prepolymer prepared from DESbis-BCB by thermal isomerization ring opening polymerization reaction were characterized and analyzed.The surface morphology and thermal stability of the films were investigated by atomic force microscopy(AFM) and thermogravimetric analysis(TGA),respectively.The results showed that the root-mean square(RMS) roughness was 0.53 nm,and the starting mass loss temperature was about 390℃.It indicated that DES-bisBCB exhibited good film-forming property and excellent thermal stability.
- bisbenzocyclobutene,
- hydrosilylation reaction,
- thermal properties,
- film-forming property
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