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Citation: HAO Yufen, LIN Weiwei, ZHAO Fengyu. Hydrogenation of 3-Nitrostyrene over Au/FeO_x Catalysts[J]. Chinese Journal of Applied Chemistry, ;2011, 28(2): 199-202. doi: 10.3724/SP.J.1095.2011.00322 shu

Hydrogenation of 3-Nitrostyrene over Au/FeO_x Catalysts

HAO Yufen ^a,b ,
LIN Weiwei ^a,b ,
ZHAO Fengyu ^a,,

1.
a State Key Laboratory of Electroanalytical Chemistry, Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b Graudate School of Chinese Academy of Sciences, Beijing

Corresponding author: ZHAO Fengyu,
Received Date: 31 May 2010
Available Online: 22 July 2010
Fund Project: 国家自然科学基金资助项目(NSFC20873139) (NSFC20873139)

Au/γ-Fe₂O₃,Au/α-Fe₂O₃ and Au/Fe₃O₄ catalysts were prepared via deposition-precipitation methods and characterized by X-ray diffraction.The catalytic performance of these catalysts was studied and compared for the hydrogenation of 3-nitrostyrene.In addition,the influences of temperature,support as well as the reaction medium were discussed.The results showed that the conversion of 3-nitrostyrene in H₂O is much higher than that in ethanol and solvent-free system,and it increased with increasing of temperature,however,the selectivity to 3-aminostyrene did not change.The catalytic activity of Au/FeO_x catalysts was in an order of Au/γ-Fe₂O₃ >Au/α-Fe₂O₃ >Au/Fe₃O₄.The different reducibility of the iron oxide supports may be the main reason for such a catalytic activity.
- gold catalyst,
- nitrostyrene,
- hydrogenation,
- iron oxide,
- water
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Hydrogenation of 3-Nitrostyrene over Au/FeO_x Catalysts