Citation:
ZHANG Lijun, LU Tianhong, LI Shiyin, DU Jiangyan. Fabrication and Application of CAP-MIP-OAP Film Electrode for Chloramphenicol Detection[J]. Chinese Journal of Applied Chemistry,
;2011, 28(3): 338-342.
doi:
10.3724/SP.J.1095.2011.00295
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The chloramphenicol(CAP) molecule-imprinted polymer(MIP) of o-aminophenol(OAP) on Pt (CAP-MIP-OAP/Pt) electrode was prepared via an electrochemical polymerization method using OAP as the functional monomer and CAP as the template molecule. This preparation method is simple. The as-prepared membrane is uniform and stable. The performances and configurations of the CAP-MIP-OAP/Pt and MIPOAP/Pt electrodes were investigated using scanning electron microscope (SEM) and electrochemical techniques. The results illustrated that the MIP-OAP/Pt electrode exhibited improved selectivity and sensitivity for the CAP detection. A linear region of the CAP detection is in the range of 4.33×10-8~3.09×10-6 mol/L. The detection limit is 2.5×10-8 mol/L. Therefore, the MIP-OAP/Pt electrode shows potential application for the enrichment and detection of CAP in the environmental water sample.
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