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Citation: WANG Zhenqing, WANG Cheng. Synthesis and Properties of Compound[InAsS₄(2,2'-bipy)]₂:AsS₄^3-(As(Ⅲ)) as One Part of the Structure[J]. Chinese Journal of Applied Chemistry, ;2011, 28(1): 77-82. doi: 10.3724/SP.J.1095.2011.00200 shu

Synthesis and Properties of Compound[InAsS₄(2,2'-bipy)]₂:AsS₄^3-(As(Ⅲ)) as One Part of the Structure

WANG Zhenqing ^a,b ,
WANG Cheng ^a,,

1.
a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b Graduate School of Chinese Academy of Sciences, Beijing

Corresponding author: WANG Cheng,
Received Date: 7 April 2010
Available Online: 5 August 2010
Fund Project: 国家基础研究项目(2007CB925101) (2007CB925101)

Compound[InAsS₄(2,2'-bipy)]₂, which contains AsS₄^3- (As(Ⅲ)) unit, was synthesized by the hydrothermal method. The compound crystalizes in monoclinic space group P2₁/c with a=0.89799(9) nm, b=2.1794(2) nm, c=1.43736(14) nm, β=91.274(2)°, V=2.8123(5) nm³. In this compound, the AsS₄^3-(As(Ⅲ)) unitis stabilized by metal-amino complex[In(2,2'-bipy)]³⁺. The effect of metal charge on the formation of this product was discussed and the band gap of the as-synthesized semiconductor is found to be 1.35 eV.
- metal arsenic sulphides,
- metal-amino complex,
- hydrothermal synthesis
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Synthesis and Properties of Compound[InAsS₄(2,2'-bipy)]₂:AsS₄^3-(As(Ⅲ)) as One Part of the Structure