Citation:
WANG Yanen, CAO Shuang, TANG Yawen, WANG Chun, MA Jingjun, LU Tianhong. Electrocatalytic Performance of the Carbon-Supported Pt-P Catalyst for Oxygen Reduction[J]. Chinese Journal of Applied Chemistry,
;2011, 28(1): 44-47.
doi:
10.3724/SP.J.1095.2011.00190
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The carbon-supported Pt-P(Pt-P/C) catalyst(m(Pt):m(P)=5:1) was prepared with NaH2 PO2 reduction method. The X-ray diffraction results indicate that the 2θ values of the Pt diffraction peaks of the Pt-P/C catalyst are slightly greater than those of the Pt/C catalyst, illustrating that P has entered into the crystal lattice of Pt and forms the Pt-P alloy. The electrochemical measurements demonstrated that the electrocatalytic performance of the Pt-P/C catalyst for the oxygen reduction is better than that of the commercial E-TEK Pt/C catalyst with 40 mV positive shift of reduction potential, which may be attributed to the P action because the average size and the relative crystallinity of the Pt-P particles in the Pt-P/C catalyst are similar to those in Pt/C catalyst.
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