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Citation: ZHOU Li, TANG Jiao-Ning, LV Wei-Zhong, LUO Zhong-Kuan, LIU Bo, WEI Ji. Effects of Alkyl Homologues on Liquid Membrane Oscillation[J]. Chinese Journal of Applied Chemistry, ;2010, 27(9): 1083-1087. doi: 10.3724/SP.J.1095.2010.90781 shu

Effects of Alkyl Homologues on Liquid Membrane Oscillation

a. College of Chemistry and Chemical Engineerin, Shenzhen University, Shenzhen 518060;
b. College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060

Received Date: 25 November 2009
Revised Date: 1 March 2010

The liquid membrane oscillation between two immiscible phases can be applied to simulate the electron transfer process in biomembrane,therefore the molecular recognition based on unique potential oscillation can be applied to chemical analysis.In this work,a liquid membrane oscillation system of water cetyltrimethyl ammonium bromide (CTAB)/n-propanol)/oil (nitromethane solution of picric acid)/water (glucose solution) was established.The influence of alkyl homologues on the liquid membrane oscillation system was studied with the presence of n-hexane,n-octane,n-decane,n-dodecane,n-tetradecane,n-hexadecane,cyclohexane or iso-octane,etc.The results indicate that the amplitude and frequency of the liquid membrane oscillation curve are closely related to the added alkanes.Therefore,it is possible to differentiate alkanes using the liquid membrane oscillation system.
- liquid membrane oscillations,
- surfactant,
- alkyl homologue,
- recognition,
- CTAB
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