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Citation: BAI Yun-Peng, SHI Lei, LIU Shu-Ying, ZHOU Hui, CUI Meng, XING Jun-Peng, YANG Xiang-Guang. A Preliminary Approach to Mimic the Formation of POPs in the Atmosphere:Chlorination of Benzene in the Gas Phase[J]. Chinese Journal of Applied Chemistry, ;2010, 27(8): 931-934. doi: 10.3724/SP.J.1095.2010.90764 shu

A Preliminary Approach to Mimic the Formation of POPs in the Atmosphere:Chlorination of Benzene in the Gas Phase

a. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
b. School of Public Health, Jilin University, Changchun 130022;
c. Graduate School of Chinese Academy of Sciences, Beijing

Received Date: 19 November 2009
Revised Date: 1 April 2010

The process of persistent organic pollutants(POPs) formation was studied by using the collision chamber of tandem mass spectrometer instead of atmospheric environment. It is found that chlorobenzenes can be formed through gas phase ion-molecule reaction in the collision chamber. And the formation of chlorobenzenes in the ion source of the mass spectrometer is also observed. When benzene content is 4 × 10^-3 Pa and acetyl chloride content is 4 × 10^-4 Pa,the chlorobenzene content reaches 5 × 10^-8 Pa,while the background of chlorobenzene is only 5 × 10^-9 Pa. So it is possible that the formation of chlorobenzene by gas phase ion-molecule reactions,because chlorobenzene is formed easier in atmosphere than that in the collision chamber.
- POPs,
- chlorobenzenes,
- gas phase ion-molecule reactions,
- atmospheric pollution
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