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Citation: LIU Lin, MA Juan-Juan, FU Ting-Ming, LI Shan-Zhong, TONG Zhi-Wei, WEI Yun-Yang. Selective Aerobic Oxidation of Alcohols Catalyzed by Octahedral Molecular Sieves in Ionic Liquids[J]. Chinese Journal of Applied Chemistry, ;2010, 27(7): 801-805. doi: 10.3724/SP.J.1095.2010.90669 shu

Selective Aerobic Oxidation of Alcohols Catalyzed by Octahedral Molecular Sieves in Ionic Liquids

a. School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, 222005;
b. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing

Received Date: 15 October 2009
Revised Date: 6 January 2010

Three manganese oxide octahedral molecular sieves(OMS-2),K-OMS-2,H-K-OMS-2 and Cu-OMS-2,were synthesized according to the literature. The structure and composition of the obtained materials were characterized by SEM and XRD. OMS-2 was applied to the selective oxidation of alcohols to generate corresponding aldehydes or ketones. The effects of reaction time and temperature on the catalytic reactions were investigated in ionic liquid [bmim]PF₆ when different OMS-2 materials were used as catalysts. The conversion and selectivity of benzylic or allylic alcohols catalyzed by H-K-OMS-2 both reached over 90%. The solvent and catalyst could be recovered from the reaction system by extraction method and vacuum distillation method,respectively. The catalytic system recovered by vacuum distillation method showed better recycling performance.
- manganese oxide,
- octahedral molecular sieve,
- alcohol,
- oxidation,
- ionic liquid
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