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Citation: WANG Jun, LIU Chang-Huan, HAN Jun, NING Meng-Meng, LI Cui-Qin. Synthesis and Surface Property of Cashew-based Surfactants[J]. Chinese Journal of Applied Chemistry, ;2010, 27(7): 866-868. doi: 10.3724/SP.J.1095.2010.90661 shu

Synthesis and Surface Property of Cashew-based Surfactants

a. College of Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing 163318;
b. Jinzhou Engineering Technology Department of Liaohe Oilfield Company, Jinzhou

Received Date: 12 October 2009
Revised Date: 8 December 2009

Cashew phenol polyoxyethylene ethers (CPE) were synthesized from cashew phenol as raw materials. In the presence of sodium hydroxide as a catalyst,a series of cashew phenol polyoxyethylene ether carboxylates(CPEC) were synthesized with CPE and chloroacetic acid. The products were structurally confirmed by FT-IR and elemental analysis. Surface properties were determined by a surface tension method. The experimental results showed that when critical micelle concentrations(CMC) of the surfactants were 9.30,8.50,8.10 and 7.71 mmol/L,the corresponding surface tensions at CMC were 28.38,28.60,30.40 and 30.00 mN/m,respectively. By means of Gibbs formula,the maximum adsorption amounts of the surfactants were 0.7087,0.7350,0.7195 and 0.7346 μmol/m²,and the minimal molecular projective areas of them were 2.3439,2.2600,2.3087 and 2.2613 nm²,respectively,on solution surface.
- cashew phenol,
- cashew phenol polyoxyethylene ether carboxylate,
- surface property
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